Bis(2,2′-bipyridine)(pyridin-2-olato)ruthenium(II) hexafluoridophosphate benzene hemisolvate

被引：3

作者：

Hamaguchi, Tomohiko ^{[1
]}

Ando, Isao ^{[1
]}

机构：

[1] Fukuoka Univ, Dept Chem, Fac Sci, Jonan Ku, Fukuoka 8140180, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

data-to-parameter ratio = 18.3; Hatom completeness 87%; mean σ(C-C) = 0.010 Å; R factor = 0.047; single-crystal X-ray study; T = 200 K; wR factor = 0.155;

D O I：

10.1107/S1600536811045454

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Ru(C5H4NO)(C10H8N2)(2)]PF6 center dot 0.5C(6)H(6), the Ru2+ cation has a distorted octahedral RuN5O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiolate ligand [Santra et al. (1997). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent molecule is situated on a twofold rotation axis.

引用

页码：M1687 / U1632

页数：12

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