Bis(2,2′-bipyridine)(pyridin-2-olato)ruthenium(II) hexafluoridophosphate benzene hemisolvate

被引：3
|
作者：
Hamaguchi, Tomohiko [1 ]
Ando, Isao [1 ]
机构：
[1] Fukuoka Univ, Dept Chem, Fac Sci, Jonan Ku, Fukuoka 8140180, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 18.3; Hatom completeness 87%; mean σ(C-C) = 0.010 Å; R factor = 0.047; single-crystal X-ray study; T = 200 K; wR factor = 0.155;
D O I：
10.1107/S1600536811045454
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ru(C5H4NO)(C10H8N2)(2)]PF6 center dot 0.5C(6)H(6), the Ru2+ cation has a distorted octahedral RuN5O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiolate ligand [Santra et al. (1997). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent molecule is situated on a twofold rotation axis.
引用
收藏
页码：M1687 / U1632
页数：12
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