The enthalpies of transfer of diaza-18-crown-6 isomers into various solvents

被引：0
|
作者：
Barannikov, VP [1 ]
Guseinov, SS [1 ]
V'yugin, AI [1 ]
机构：
[1] Russian Acad Sci, Inst Chem Solut, Ivanovo, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2004年 / 78卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The enthalpies of solution of the 1,7-diaza-18-crown-6 and 1,10-diaza-18-crown-6 isomers were studied calorimetrically in tetrachloromethane, benzene, chloroform, pyridine, acetone, acetonitrile, DMFA, DMSO, methanol, and water at 298.15 K. The enthalpies of transfer of the crown ethers corrected for the different enthalpies of formation of cavities changed in parallel with the dipole moment of solvent molecules. Specific interactions between the crown ethers and water, chloroform, and methanol were observed. Some strengthening of specific interactions of 1,7-diaza-18-crown-6 compared with 1,10-diaza-18-crown-6 is explained by differences in the conformational behavior of the isomeric molecules in solution.
引用
收藏
页码：154 / 157
页数：4
相关论文
共 50 条
  • [41] Preparation, characterization and CD spectrum of lanthanide nitrate complexes with chiral diaza-18-crown-6
    Zhu, WX
    Song, YY
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 1999, 15 (05) : 590 - 594
  • [42] Crystal Structure and Vibrational Spectra of N,N"-Di(perfluorotolyl)diaza-18-crown-6
    L. Kh. Minacheva
    I. S. Ivanova
    E. N. Pyatova
    V. S. Sergienko
    A. Yu. Tsivadze
    G. A. Artamkina
    I. P. Beletskaya
    Doklady Chemistry, 2003, 389 : 54 - 57
  • [43] SORPTION OF EUROPIUM BY A POLYMERIC SORBENT CONTAINING DIAZA-18-CROWN-6 AND ITS ANALYTICAL APPLICATION
    BELTYUKOVA, SV
    KRAVCHENKO, TB
    ZITSMANIS, AK
    BALAMTSARASHVILI, GM
    ROSKA, AS
    MALINKA, EV
    JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1990, 45 (06): : 791 - 794
  • [44] AN INCLUSION COMPLEX OF URANYL IN A DIAZACROWN - (DIAZA-18-CROWN-6)(2+).2CF(3)SO(3)(-) AND [UO2(DIAZA-18-CROWN-6)](+).CF3SO3-
    THUERY, P
    KELLER, N
    LANCE, M
    SABATTIE, JM
    VIGNER, JD
    NIERLICH, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 801 - 805
  • [45] KINETICS AND MECHANISMS OF COMPLEX-FORMATION OF URANYL-ION WITH 18-CROWN-6 AND DIAZA-18-CROWN-6 LIGANDS IN PROPYLENE CARBONATE
    FUX, P
    LAGRANGE, J
    LAGRANGE, P
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (21) : 5927 - 5931
  • [46] Study of complex formation between 18-crown-6 and diaza-18-crown-6 with uranyl cation (UO22+) in some binary mixed aqueous and non-aqueous solvents
    M. Ansari Fard
    G. H. Rounaghi
    M. Chamsaz
    K. Taheri
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2009, 64 : 49 - 56
  • [47] ENTHALPIES AND ENTROPIES OF COMPLEXATION OF SILVER(I) AND DIAZA-18-CROWN ETHERS IN POLAR-SOLVENTS
    BURCHARD, T
    FIRMAN, P
    SCHNEIDER, H
    COX, BG
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1994, 98 (12): : 1534 - 1540
  • [48] New quaternary ammonium salts and metal complexes of organylheteroacetic acids with diaza-18-crown-6 ether
    Adamovich, S. N.
    Mirskova, A. N.
    Mirskov, R. G.
    Perminova, O. M.
    Chipanina, N. N.
    Aksamentova, T. N.
    Voronkov, M. G.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2010, 80 (05) : 1007 - 1010
  • [49] NEW SYMMETRICAL CHIRAL DIBENZYL-SUBSTITUTED AND DIPHENYL-SUBSTITUTED DIAMIDO-18-CROWN-6, DITHIONOAMIDO-18-CROWN-6, DIAZA-18-CROWN-6, AND AZAPYRIDINO-18-CROWN-6 LIGANDS
    HUSZTHY, P
    OUE, M
    BRADSHAW, JS
    ZHU, CY
    WANG, TM
    DALLEY, NK
    CURTIS, JC
    IZATT, RM
    JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (20): : 5383 - 5394
  • [50] New quaternary ammonium salts and metal complexes of organylheteroacetic acids with diaza-18-crown-6 ether
    S. N. Adamovich
    A. N. Mirskova
    R. G. Mirskov
    O. M. Perminova
    N. N. Chipanina
    T. N. Aksamentova
    M. G. Voronkov
    Russian Journal of General Chemistry, 2010, 80 : 1007 - 1010
12345