N,N′-dibromo-N,N′-1,2-ethanediylbis(benzenesulphonamide) (BNBBS):: a safe, neutral and efficient reagent for the oxidation of primary and secondary alcohols to corresponding carbonyl compounds under mild conditions

被引：0

作者：

Rostami, Amin ^{[2
]}

Mahboubifar, Marjan ^{[1
]}

Khazaei, Ardeshir ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran

[2] Univ Kurdistan, Dept Chem, Fac Sci, Sanandaj, Iran

来源：

SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE | 2008年 / 61卷

关键词：

oxidation; alcohols; carbonyl compounds; N,N '-dibromo-N,N '-1,2-ethanediylbis(benzenesulphonamide);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds can be carried out with N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide) in good to high yield of products in CH2Cl2 at room temperature. Primary (aliphatic, benzylic and allylic) alcohols are oxidized with no over-oxidation to carboxylic acids.

引用

页码：9 / 12

页数：4

共 43 条

[41] Efficient and selective oxidation of benzylic alcohols to carbonyl compounds using O2 catalysed by [nBu4N]4W10O32/SiO2 under photoirradiation
Farhadi, S
Afshari, M
JOURNAL OF CHEMICAL RESEARCH, 2006, (03) : 188 - 191
[42] Erratum: Selective and rapid oxidation of primary, allylic and benzylic alcohols to the corresponding carbonyl compounds with NaNO2-acetic anhydride under mild and solvent-free conditions (Journal of the Chemical Society. Perkin Transactions 1 (2000) (3559))
Bandgar, Babasaheb P.
Sadavarte, Vaibhav S.
Uppalla, Lavkumar S.
Journal of the Chemical Society. Perkin Transactions 1, 2001, (09):
[43] Surface-mediated organometallic synthesis:: The role of the oxidation state and of ancillary ligands in the high-yield and selective syntheses of platinum carbonyl dianions [Pt3(CO)6]n2- (n=6, 5, 4, 3) by reductive carbonylation under mild conditions and in the presence of surface basicity of various silica-supported Pt(IV) or Pt(II) compounds
Dragonetti, Claudia
Ceriotti, Alessandro
Roberto, Dominique
Ugo, Renato
ORGANOMETALLICS, 2007, 26 (02) : 310 - 315

← 1 2 3 4 5 →