N,N′-dibromo-N,N′-1,2-ethanediylbis(benzenesulphonamide) (BNBBS):: a safe, neutral and efficient reagent for the oxidation of primary and secondary alcohols to corresponding carbonyl compounds under mild conditions

被引：0

作者：

Rostami, Amin ^{[2
]}

Mahboubifar, Marjan ^{[1
]}

Khazaei, Ardeshir ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran

[2] Univ Kurdistan, Dept Chem, Fac Sci, Sanandaj, Iran

来源：

SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE | 2008年 / 61卷

关键词：

oxidation; alcohols; carbonyl compounds; N,N '-dibromo-N,N '-1,2-ethanediylbis(benzenesulphonamide);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds can be carried out with N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide) in good to high yield of products in CH2Cl2 at room temperature. Primary (aliphatic, benzylic and allylic) alcohols are oxidized with no over-oxidation to carboxylic acids.

引用

页码：9 / 12

页数：4

共 43 条

[21] N-methyl piperidinium chlorochromate adsorbed on alumina: A new and selective reagent for the oxidation of benzylic alcohols to their corresponding carbonyl compounds
Tajbakhsh, M
Ghaemi, M
Sarabi, S
Ghassemzadeh, M
Heravi, MM
MONATSHEFTE FUR CHEMIE, 2000, 131 (11): : 1213 - 1216
[22] N-Methyl Piperidinium Chlorochromate Adsorbed on Alumina: A New and Selective Reagent for the Oxidation of Benzylic Alcohols to their Corresponding Carbonyl Compounds
Mahmood Tajbakhsh
Moosa Ghaemi
Siavosh Sarabi
Mitra Ghassemzadeh
Majid M. Heravi
Monatshefte für Chemie / Chemical Monthly, 2000, 131 : 1213 - 1216
[23] Facile and chemoselective microwave-assisted cleavage of oximes to their corresponding carbonyl compounds using N,N′-dibromo- N,N′-1,3propylene-bis[(4-methylphenyl)sulfonamide] as a deoximating reagent
Khazaei, A
Manesh, AA
Ghasemi, AH
SYNTHESIS-STUTTGART, 2004, (17): : 2784 - 2786
[24] Potassium phthalimide-N-oxyl:: An efficient catalyst for cyanosilylation of carbonyl compounds under mild conditions
Dekamin, Mohammad G.
Javanshir, Shahrzad
Naimi-Jamal, M. Reza
Hekmatshoar, Rahim
Mokhtari, Javad
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 283 (1-2) : 29 - 32
[25] Oxidative aromatization of 3,5-disubstituted isoxazolines to the corresponding isoxazoles with N′,N′,N′N′-tetrabromobenzene-1,3-disolphonamide (TBBDS) and 1,3-dibromo-5,5-dimethylhydantoin (DBH) as efficient reagents under mild reaction conditions
Azarifar, Davood
Maleki, Behrooz
Mohammadi, Kobra
HETEROCYCLES, 2007, 71 (03) : 683 - 689
[26] Efficient and chemoselective conversion of carbonyl compounds to 1,3-dioxanes catalyzed with N-bromosuccinimide under almost neutral reaction conditions
Karimi, B
Ebrahimian, GR
Seradj, H
ORGANIC LETTERS, 1999, 1 (11) : 1737 - 1739
[27] High efficient copper-promoted N-arylation of secondary and primary amines with triarylbismuth reagents under mild conditions
Zhou, Xuehao
Ma, Huifang
Xie, Jianwei
JOURNAL OF MOLECULAR STRUCTURE, 2023, 1294
[28] Efficient transition-metal-free oxidation of benzylic and secondary alcohols to the carbonyl compounds using an N-bromosuccinimide/NH4Cl system
Jain, SL
Sain, B
SYNTHETIC COMMUNICATIONS, 2006, 36 (10) : 1459 - 1462
[29] Ionic liquid 1-(4-nitritobutyl)-3-methylimidazolium chloride as a new reagent for the efficient N-nitrosation of secondary amines under mild conditions
Valizadeh, Hassan
Gholipour, Hamid
Shomali, Ashkan
MONATSHEFTE FUR CHEMIE, 2012, 143 (03): : 467 - 470
[30] Ionic liquid 1-(4-nitritobutyl)-3-methylimidazolium chloride as a new reagent for the efficient N-nitrosation of secondary amines under mild conditions
Hassan Valizadeh
Hamid Gholipour
Ashkan Shomali
Monatshefte für Chemie - Chemical Monthly, 2012, 143 : 467 - 470

← 1 2 3 4 5 →