N,N′-dibromo-N,N′-1,2-ethanediylbis(benzenesulphonamide) (BNBBS):: a safe, neutral and efficient reagent for the oxidation of primary and secondary alcohols to corresponding carbonyl compounds under mild conditions

被引：0

作者：

Rostami, Amin ^{[2
]}

Mahboubifar, Marjan ^{[1
]}

Khazaei, Ardeshir ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran

[2] Univ Kurdistan, Dept Chem, Fac Sci, Sanandaj, Iran

来源：

SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE | 2008年 / 61卷

关键词：

oxidation; alcohols; carbonyl compounds; N,N '-dibromo-N,N '-1,2-ethanediylbis(benzenesulphonamide);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds can be carried out with N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide) in good to high yield of products in CH2Cl2 at room temperature. Primary (aliphatic, benzylic and allylic) alcohols are oxidized with no over-oxidation to carboxylic acids.

引用

页码：9 / 12

页数：4

共 43 条

[1] Efficient, Solvent-Free and Rapid Oxidation of Alcohols to Carbonyl Compounds with N,N′-Dibromo-N,N′-1,2-ethanediylbis(benzene sulfonamide)
Mahboubifar, M.
Khazaei, A.
Rostami, A.
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (02) : 829 - 831
[2] N,N′-DIBROMO-N,N′-1,2-ETHANEDIYLBIS(BENZENE SULFONAMIDE) AS AN EFFICIENT CATALYST FOR ACETYLATION AND FORMYLATION OF ALCOHOLS UNDER MILD CONDITIONS
Khazaei, Ardeshir
Rostami, Amin
Rosta, Zahra
Alavi, Ali
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (01) : 181 - 186
[3] N,N′-Dibromo-N,N′-1,2-ethanediylbis(benzene sulfonamide) as a novel N-bromo reagent catalyzed tetrahydropyranylation/depyranylation of alcohols and phenols under mild conditions
Khazaei, Ardeshir
Rostami, Amin
Mahboubifar, Marjan
CATALYSIS COMMUNICATIONS, 2007, 8 (03) : 383 - 388
[4] The application of N,N′-dibromo-N,N′-1,2-ethanediylbis-(p-toluenesulphonamide) as a powerful reagent for the oxidation of primary and secondary alcohols to aldehydes and ketones
Ghorbani-Vaghei, R
Khazaei, A
TETRAHEDRON LETTERS, 2003, 44 (40) : 7525 - 7527
[5] A new application of N,N′-dibromo-N,N′-1,2-ethanediylbis(p-toluenesulfonamide) as selective and efficient reagent for the oxidation of various thiols to disulfides
Khazaei, A
Rostami, A
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2005, 180 (02) : 555 - 557
[6] Microwave assisted facile cleavage of 2,4-dinitrophenylhydrazones to the corresponding carbonyl compounds with N,N′-dibromo-N,N′-1,2-ethanediylbis(p-toluenesulphonamide)
Khazaei, A
Vaghei, RG
MOLECULES, 2002, 7 (05) : 465 - 468
[7] The application of N,N′-dibromo-N,N′-1,2-ethanediylbis (p-toluenesulphonamide) as a powerful reagent for deoximation of various oximes
Khazaei, A
Vaghei, RG
Tajbakhsh, M
TETRAHEDRON LETTERS, 2001, 42 (30) : 5099 - 5100
[8] N,N'-dibromo-N,N'-1,2-ethanediylbis(p-toluenesulphonamide) as a useful reagent for oxidation of 1,3,5-trisubstituted pyrazolines
Ghorbani-Vaghei, R
Azarifar, D
Maleki, B
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2004, 25 (07) : 953 - 954
[9] N,N'-dibromo-N,N'-1,2-ethanediylbis (benzene sulfonamide) as a novel N-Bromo Reagent-catalyzed trimethylsilylation of alcohols and phenol with hexamethyldisilazane in both solution and solvent-free conditions
Khazaei, Ardeshir
Rostami, Amin
Rahmati, Sadegh
Mahboubifar, Marjan
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (03) : 537 - 544
[10] Microwave assisted facile cleavage of 2,4-dinitrophenylhydrazones to their corresponding carbonyl compounds with N,N′-dibromo-N,N′-1,2-ethanediylbis(p-toluenesulphonamide) (vol 7, pg 717, 2002)
Khazaei, A
Vaghei, RG
MOLECULES, 2005, 10 (01) : 317 - 317

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