Interlocking frameworks. A consequence of enlarging spacers from 4-pyridinecarboxylate to 4-(4-pyridyl)benzoate

被引：37
|
作者：
Lu, TB
Luck, RL
机构：
[1] Michigan Technol Univ, Dept Chem, Houghton, MI 49931 USA
[2] Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2003年 / 351卷
关键词：
pyridinecarboxylate; diamondoid; geometric isomers; crystal structures;
D O I：
10.1016/S0020-1693(03)00215-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystallinity of evacuated framework polymer {[Cu(pyca)].2H(2)O}(x), pyca = 4-pyridinecarboxyl ate, is preserved after removal of the interstitial solvent molecules. Staying with Cu2+ and enlarging the spacers from 4-pyridinecarboxylate to 4-(4-pyridyl)benzoate results in a sixfold interpenetrating diamondoid framework. This is composed of different extended arrays in a 4:2 ratio each individually composed of one of two geometric isomers of Cu (distorted octahedral and square pyramidal) found in the crystal. (C) Elsevier B.V. All rights reserved.
引用
收藏
页码：345 / 355
页数：11
相关论文
共 50 条
  • [1] 4-(4-Pyridyl)pyridinium triiodide
    Kochel, Andrzej
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O5605 - O5606
  • [2] SYNTHESIS OF 4-(4-PYRIDYL) OXAZOLES
    BRANA, MF
    CASTELLANO, JM
    DEMIGUEL, P
    POSADA, P
    SANZ, CR
    MIGALLON, AS
    TETRAHEDRON, 1994, 50 (33) : 10061 - 10072
  • [3] Syntheses and Characterizations of the Lanthanide Compounds with 4-(4-Pyridyl) benzoate and 2,6-Pyridinedicarboxylate as Ligands
    Zhang Man-Bo
    Zhang Mei-Zhi
    Chen Xing
    Hu Rui-Xiang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36 (05) : 825 - 830
  • [4] 4-(4-Pyridyl)pyridinium perchlorate methanol solvate
    Gao, Yu-Hua
    Wu, De-Ming
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1068 - U1710
  • [5] Syntheses and Characterizations of the Lanthanide Compounds with 4-(4-Pyridyl)benzoate and 2,6-Pyridinedicarboxylate as Ligands
    张漫波
    张美智
    陈星
    胡瑞祥
    Chinese Journal of Structural Chemistry, 2017, 36 (05) : 825 - 830
  • [6] Methanol mediated crystal transformations in a solvatochromic metal organic framework constructed from Co(II) and 4-(4-pyridyl) benzoate
    Mehlana, Gift
    Ramon, Gaelle
    Bourne, Susan A.
    CRYSTENGCOMM, 2013, 15 (45): : 9521 - 9529
  • [7] Synthesis of the ethyl esters of 4-(3-pyridyl)- and 4-(4-pyridyl)-2-oxobutenoic acids
    Sile Dz.
    Slavinska V.A.
    Rozental G.
    Popelis J.
    Balodis Yu.
    Lukevics E.
    Chemistry of Heterocyclic Compounds, 2002, 38 (03) : 287 - 291
  • [8] Synthesis of ethyl esters of 4-(3-pyridyl)- and 4-(4-pyridyl)-2-oxobutenoic acids
    Sile, DE
    Slavinskaya, VA
    Rozentals, GF
    Popelis, J
    Balodis, JJ
    Lukevics, E
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2002, (03): : 321 - 325
  • [9] Mesomorphic properties of 4-(4-pyridyl)-benzoic acid esters
    Odomeniene, O
    Adomenas, P
    Gleiznys, A
    Poloudina, L
    Gotoh, Y
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2001, 365 : 1031 - 1035
  • [10] Bis{4-[(4-pyridyl)ethenyl]pyridinium} 4-sulfonatobenzoate trihydrate
    Zhang, LP
    Zhu, LG
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1529 - O1531
12345