Halogen Addition to a Frustrated Lewis Pair

被引：18
|
作者：
Froemel, Silke [1 ]
Froehlich, Roland [1 ]
Daniliuc, Constantin G. [1 ]
Kehr, Gerald [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 23期
关键词：
Frustrated Lewis pairs; Phosphorus; Boron; Halogens; Zwitterions; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; SOLID-STATE; CRYSTAL-STRUCTURES; REAGENT PH3PCL2; ALKYL CHLORIDES; BORANE; PHOSPHINES; ALCOHOLS; BIS(PENTAFLUOROPHENYL)BORANE;
D O I：
10.1002/ejic.201200288
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactive intramolecular frustrated Lewis pair (FLP) Mes2PCH2CH2B(C6F5)2 reacts rapidly with thionyl chloride to yield the zwitterionic chlorination product [Mes2PCl+]CH2CH2[BCl(C6F5)2]. Analogous zwitterionic products were obtained by the reaction of the FLP with chlorine or bromine. Compounds [Mes2PX+]CH2CH2[BX(C6F5)2] (X = Cl, Br) were characterized by X-ray crystal structure analyses.
引用
收藏
页码：3774 / 3779
页数：6
相关论文
共 50 条
  • [1] "Frustrated Lewis pair" hydrogenations
    Stephan, Douglas W.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (30) : 5740 - 5746
  • [2] Frustrated Lewis pair chemistry
    Stephan, Douglas W.
    Erker, Gerhard
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2017, 375 (2101):
  • [3] Frustrated Lewis Pair Nanoribbons
    Janesko, Benjamin G.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (31): : 16467 - 16472
  • [4] A Frustrated and Confused Lewis Pair
    McQuilken, Alison C.
    Dao, Quang Minh
    Cardenas, Allan Jay P.
    Bertke, Jeffery A.
    Grimme, Stefan
    Warren, Timothy H.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (46) : 14333 - 14337
  • [5] Unusual borane addition to conjugated dienylphosphanes under frustrated Lewis pair conditions
    Krupski, Sergei
    Kehr, Gerald
    Daniliuc, Constantin G.
    Erker, Gerhard
    DALTON TRANSACTIONS, 2016, 45 (14) : 6111 - 6117
  • [6] Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair
    Liedtke, Rene
    Scheidt, Felix
    Ren, Jinjun
    Schirmer, Birgitta
    Cardenas, Allan Jay P.
    Daniliuc, Constantin G.
    Eckert, Hellmut
    Warren, Timothy H.
    Grimme, Stefan
    Kehr, Gerald
    Erker, Gerhard
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (25) : 9014 - 9027
  • [7] Organometallic frustrated Lewis pair chemistry
    Erker, Gerhard
    DALTON TRANSACTIONS, 2011, 40 (29) : 7475 - 7483
  • [8] Frustrated Lewis Pair Catalyzed Hydrogenations
    Paradies, Jan
    SYNLETT, 2013, 24 (07) : 777 - 780
  • [9] Frustrated Lewis Pair Catalyzed Reactions
    Zhou, Rundong
    Tavandashti, Zoleykha Pirhadi
    Paradies, Jan
    SYNOPEN, 2023, 07 (01): : 46 - 57
  • [10] Frustrated Lewis pair chemistry of CO
    Stephan, Douglas W. W.
    CHEMICAL SOCIETY REVIEWS, 2023, 52 (14) : 4632 - 4643
12345