Thin Film Electrodes of Prussian Blue Analogues with Rapid Li+ Intercalation

被引：42

作者：

Moritomo, Yutaka ^{[1
,2
,3
]}

Takachi, Masamitsu ^{[3
]}

Kurihara, Yutaro ^{[1
]}

Matsuda, Tomoyuki ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Tsukuba, Ibaraki 3058571, Japan

[3] Univ Tsukuba, Sch Sci & Engn, Tsukuba, Ibaraki 3058571, Japan

来源：

APPLIED PHYSICS EXPRESS | 2012年 / 5卷 / 04期

关键词：

BATTERIES;

D O I：

10.1143/APEX.5.041801

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A new class of electrode materials are being intensively investigated to achieve a low-cost Li+ secondary battery (LIB) with a high discharge rate. Here, we investigated the discharge rate in thin film electrodes of the Prussian blue analogues (Li,Na)(4y-2)M[Fe(CN)(6)](y)zH(2)O (M = Ni, Co, Mn, and Cd). Except for the Co compound, the capacities at 100C exceed 60% of those at 1 C. We further investigated the electronic and crystal structures of Prussian blue analogues against Li+ concentration (x). On the basis of these data, we will discuss the origin of the rapid Li+ intercalation. (C) 2012 The Japan Society of Applied Physics

引用

页数：3

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