Thin Film Electrodes of Prussian Blue Analogues with Rapid Li+ Intercalation

被引：42
|
作者：
Moritomo, Yutaka [1 ,2 ,3 ]
Takachi, Masamitsu [3 ]
Kurihara, Yutaro [1 ]
Matsuda, Tomoyuki [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
[2] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Tsukuba, Ibaraki 3058571, Japan
[3] Univ Tsukuba, Sch Sci & Engn, Tsukuba, Ibaraki 3058571, Japan
来源：
APPLIED PHYSICS EXPRESS | 2012年 / 5卷 / 04期
关键词：
BATTERIES;
D O I：
10.1143/APEX.5.041801
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
A new class of electrode materials are being intensively investigated to achieve a low-cost Li+ secondary battery (LIB) with a high discharge rate. Here, we investigated the discharge rate in thin film electrodes of the Prussian blue analogues (Li,Na)(4y-2)M[Fe(CN)(6)](y)zH(2)O (M = Ni, Co, Mn, and Cd). Except for the Co compound, the capacities at 100C exceed 60% of those at 1 C. We further investigated the electronic and crystal structures of Prussian blue analogues against Li+ concentration (x). On the basis of these data, we will discuss the origin of the rapid Li+ intercalation. (C) 2012 The Japan Society of Applied Physics
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页数：3
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