Fast and Living Ring-Opening Polymerization of α-Amino Acid N-Carboxyanhydrides Triggered by an "Alliance" of Primary and Secondary Amines at Room Temperature

被引：49
|
作者：
Zhao, Wei [1 ]
Gnanou, Yves [2 ]
Hadjichristidis, Nikos [1 ]
机构：
[1] KAUST, Phys Sci & Engn Div, KAUST Catalysis Ctr, Polymer Synth Lab, Thuwal 23955, Saudi Arabia
[2] KAUST, Phys Sci & Engn Div, Thuwal 23955, Saudi Arabia
来源：
BIOMACROMOLECULES | 2015年 / 16卷 / 04期
关键词：
BLOCK COPOLYPEPTIDES; NCA POLYMERIZATION; POLYPEPTIDES; COPOLYMERS; CHEMISTRY; MECHANISM; KINETICS; STRATEGY;
D O I：
10.1021/acs.biomac.5b00134
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A novel highly efficient strategy, based on an alliance of primary and secondary amine initiators, was successfully developed allowing the fast and living ring-opening polymerization (ROP) of alpha-amino acid N-carboxyanhydrides (NCAs) at room temperature.
引用
收藏
页码：1352 / 1357
页数：6
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