Primary ammonium/tertiary amine-mediated controlled ring opening polymerisation of amino acid N-carboxyanhydrides

被引:47
|
作者
Vacogne, Charlotte D. [1 ]
Schlaad, Helmut [2 ]
机构
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
[2] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany
关键词
BLOCK-COPOLYMERS; POLYPEPTIDE; NCA; COMPLEXES;
D O I
10.1039/c5cc06905j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Stable commercial primary ammonium chlorides were combined with tertiary amines to initiate the controlled ring opening polymerisation of amino acid N-carboxyanhydrides to yield polypeptides with defined end group structure, predetermined molar mass and narrow molar mass distribution.
引用
收藏
页码:15645 / 15648
页数:4
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