Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br

被引：86
|
作者：
Zhang, Min [1 ,2 ]
Pan, Shi-Lie [1 ]
Fan, Xiao-Yun [1 ]
Zhou, Zhong-Xiang [1 ]
Poeppelmeier, Kenneth R. [3 ]
Yang, Yun [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
CRYSTENGCOMM | 2011年 / 13卷 / 08期
基金：
中国国家自然科学基金;
关键词：
SINGLE-CRYSTALS; UV ABSORPTION; NLO CRYSTALS; GENERATION; TELLURITE; DESIGN;
D O I：
10.1039/c0ce00725k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A high quality single crystal of K3B6O10Br has been grown with sizes up to 14 x 12 x 7 mm(3) by the top-seeded solution growth method. It crystallizes in a noncentrosymetric trigonal system, space group R3m with cell parameters a = 10.1153(8)angstrom, c = 8.8592(14)angstrom, Z = 3, V = 785.02(15)angstrom(3). K3B6O10Br has a three-dimensional network consisting of B6O13 units, which are surrounded by a K-Br framework. A transmission spectrum of the K3B6O10Br crystal was reported. Its refractive indices were measured by a minimum deviation technique and fit to Sellmeier equations. Nonlinear optical measurements demonstrate that the material has second harmonic generation properties, with efficiency approximately three times that of KH2PO4.
引用
收藏
页码：2899 / 2903
页数：5
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