Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br

被引：86
|
作者：
Zhang, Min [1 ,2 ]
Pan, Shi-Lie [1 ]
Fan, Xiao-Yun [1 ]
Zhou, Zhong-Xiang [1 ]
Poeppelmeier, Kenneth R. [3 ]
Yang, Yun [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
CRYSTENGCOMM | 2011年 / 13卷 / 08期
基金：
中国国家自然科学基金;
关键词：
SINGLE-CRYSTALS; UV ABSORPTION; NLO CRYSTALS; GENERATION; TELLURITE; DESIGN;
D O I：
10.1039/c0ce00725k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A high quality single crystal of K3B6O10Br has been grown with sizes up to 14 x 12 x 7 mm(3) by the top-seeded solution growth method. It crystallizes in a noncentrosymetric trigonal system, space group R3m with cell parameters a = 10.1153(8)angstrom, c = 8.8592(14)angstrom, Z = 3, V = 785.02(15)angstrom(3). K3B6O10Br has a three-dimensional network consisting of B6O13 units, which are surrounded by a K-Br framework. A transmission spectrum of the K3B6O10Br crystal was reported. Its refractive indices were measured by a minimum deviation technique and fit to Sellmeier equations. Nonlinear optical measurements demonstrate that the material has second harmonic generation properties, with efficiency approximately three times that of KH2PO4.
引用
收藏
页码：2899 / 2903
页数：5
相关论文
共 50 条
  • [21] Potassium bromo-borate K3[B6O10]Br—A new nonlinear optical material
    A. G. Al-Ama
    E. L. Belokoneva
    S. Yu. Stefanovich
    O. V. Dimitrova
    N. N. Mochenova
    Crystallography Reports, 2006, 51 : 225 - 230
  • [22] K3B6O10Br非线性光学晶体的生长及性质研究
    张敏
    潘世烈
    王颖
    杨云
    张方方
    人工晶体学报, 2012, 41(S1) (S1) : 170 - 174
  • [23] K3B6O10Br紫外非线性光学晶体研究进展（特邀）
    张敏
    王浩然
    张玲
    激光与光电子学进展, 2024, 61 (03) : 143 - 150
  • [24] Potassium bromo-borate K3[B6O10]Br -: A new nonlinear optical material
    Al-Ama, A. G.
    Belokoneva, E. L.
    Stefanovich, S. Yu.
    Dimitrova, O. V.
    Mochenova, N. N.
    CRYSTALLOGRAPHY REPORTS, 2006, 51 (02) : 225 - 230
  • [25] Comparison of high average-power femtosecond green and ultraviolet laser emissions generated by K3B6O10Br and K3B6O10Cl nonlinear crystals
    Yan, Xin
    Zhang, Ling
    Zhu, Jiangfeng
    Li, Ya
    Liu, Jiang
    Zhang, Min
    OPTIK, 2023, 283
  • [26] 非线性光学晶体K3B6O10Br的生长与光电性能研究
    刘青雄
    王天予
    刘孚安
    吴倩
    尹延如
    赫崇君
    高泽亮
    夏明军
    人工晶体学报, 2023, 52 (07) : 1296 - 1301
  • [27] Femtosecond green and ultraviolet lasers generated using second-harmonic generation based on K3B6O10Br nonlinear optical crystals
    Zhang, Ling
    Long, Yun
    Zhang, Min
    Li, Chunyong
    Wang, Ying
    Pan, Shilie
    Zhang, Xingwang
    Zhang, Xin
    OPTICAL ENGINEERING, 2020, 59 (05)
  • [28] Research on crystal growth and properties of a new nonlinear optical crystal:Bismuth borate BiB3O6
    TENG Bing
    ChineseScienceBulletin, 2001, (21) : 1783 - 1785
  • [29] Research on crystal growth and properties of a new nonlinear optical crystal:: Bismuth borate BiB3O6
    Teng, B
    Wang, JY
    Wang, ZP
    Jiang, HD
    Song, RB
    Liu, H
    Hu, XB
    Liu, YG
    Wei, JQ
    Shao, ZS
    CHINESE SCIENCE BULLETIN, 2001, 46 (21): : 1783 - 1785
  • [30] High power green picosecond laser and high efficiency ultraviolet femtosecond laser through second harmonic generation using K3B6O10Br crystal
    Tang, Guangxin
    Yan, Xin
    Zhang, Min
    Luan, Zhihao
    Li, Hongfeng
    Zhang, Qiulin
    Zhang, Ling
    Wang, Lirong
    EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2022, 97
12345