Organoiodine-induced hydroxylation as well as enantioselective alkoxylation/hydroxylation of allylic alcohols via 1,2-aryl migration

被引：4
|
作者：
Hu, Liangzhen [1 ]
Gao, Tianyong [1 ]
Deng, Qingfu [1 ]
Xiong, Yan [1 ,2 ,3 ]
机构：
[1] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 401331, Peoples R China
[2] Sch Chem & Environm Engn, Xinjiang 830091, Peoples R China
[3] Xinjiang Inst Engn, Key Lab Coal Based Energy & Chem Ind, Xinjiang 830091, Peoples R China
来源：
TETRAHEDRON | 2021年 / 95卷
基金：
中国国家自然科学基金;
关键词：
Organoiodine; Alkyoxylation; hydroxylation; Allylic alcohols; Enantioselective; 1; 2-aryl migration; P-IODOTOLUENE DIFLUORIDE; CATALYZED TRIFLUOROMETHYLATION; ALPHA-FLUORINATION; EFFICIENT APPROACH; CARBONYL-COMPOUNDS; BOND FORMATION; REARRANGEMENT; FUNCTIONALIZATION; KETONES;
D O I：
10.1016/j.tet.2021.132334
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method for the hydroxylation of allylic alcohols using [hydroxyl(tosyloxy)iodo]benzene (HTIB) as both oxidant and reagent has been developed. Meanwhile, the enantioselective alkyoxylation as well as hydroxylation catalyzed by simple chiral iodine benzene have been developed through the in situ hypervalent iodine synthesis strategy. (c) 2021 Elsevier Ltd. All rights reserved.
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页数：9
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