Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

被引：51
|
作者：
Huang, Hong-Li [1 ]
Yan, Hang [1 ]
Yang, Chao [1 ]
Xia, Wujiong [1 ]
机构：
[1] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, State Key Lab Urban Water Resource & Environm, Harbin 150080, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 23期
关键词：
PHOTOREDOX CATALYSIS; VICINAL DIFUNCTIONALIZATION; RADICAL-ADDITION; BOND FORMATION; ALKENES; FUNCTIONALIZATION; TRIFLUOROMETHYLATION; EFFICIENT; PHOTOCATALYSIS; REARRANGEMENT;
D O I：
10.1039/c4cc10321a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A photocatalytic process for selective arylalkylation of allylic alcohols with a-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize a-aryl-b-alkylated ketones via unique 1,2-arylmigration. The procedure is highlighted by its operational simplicity and mild reaction conditions.
引用
收藏
页码：4910 / 4913
页数：4
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