Advances in Radical Mediated 1,2-Aryl Migration Reactions of α,α-Diarylallyl Alcohols

被引：3

作者：

Zhang Jiantao ^{[1
]}

Deng Yawen ^{[1
]}

Mo Nuolin ^{[1
]}

Chen Lianfen ^{[2
]}

机构：

[1] Guangdong Univ Petrochem Technol, Coll Chem, Maoming 525000, Guangdong, Peoples R China

[2] Zhaoqing Univ, Sch Environm & Chem Engn, Zhaoqing 526061, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 02期

基金：

中国国家自然科学基金;

关键词：

allyl alcohols; migration reaction; semipinacol; neophyl rearrangement; carbonyl compounds; ALLYLIC ALCOHOLS; CATALYZED TRIFLUOROMETHYLATION; CARBONYL-COMPOUNDS; ALKENES; ALPHA; ARYL; REARRANGEMENT; KETONES; ARYLTRIFLUOROMETHYLATION; DIFUNCTIONALIZATION;

D O I：

10.6023/cjoc202208028

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As widely used building blocks, allyl alcohols can directly participate in the synthesis reaction without pre-functionalization. In recent years, the migration reaction of allyl alcohols has received great attention, and such reactions are often realized by semipinacol or neophyl rearrangement, providing a powerful strategy for the synthesis of various important carbonyl compounds. The latest progress of radical-initiated group migration reactions involving diaryl allyl alcohols as synthons systematically is reviewed, the scope, limitations and some mechanisms of the reaction are discussed, and the challenges and future development trends in this field are prospected.

引用

页码：426 / 435

页数：10

共 66 条

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