Formation of Nanostructured Carbon from [Ni(NH3)6]3[Fe(CN)6]2

被引：7
|
作者：
Domonov, Denis P. [1 ]
Pechenyuk, Sophiya I. [1 ]
Belyaevskii, Alexander T. [1 ]
Yusenko, Kirill V. [2 ]
机构：
[1] RAS, KSC ICTREMR, Tananaev Inst Chem & Technol Rare Elements & Mine, Akad Rodok 26a, Apatity 184209, Murmansk Region, Russia
[2] Bundesanstalt Mat Forsch & Prufung BAM, Richard Willstatter Str 11, D-12489 Berlin, Germany
来源：
NANOMATERIALS | 2020年 / 10卷 / 02期
关键词：
double complex compound; thermal decomposition; carbon materials; MICROSTRUCTURAL CHANGES; HEXACYANOFERRATE(III); COMPLEXES; THERMOLYSIS; PRECURSORS; SYSTEM; METAL;
D O I：
10.3390/nano10020389
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The products of thermal decomposition in an argon atmosphere of [Ni(NH3)(6)](3)[Fe(CN)(6)](2) as a precursor has been studied. Decomposition products were studied up to 800 degrees C. Above 600 degrees C, all coordination bonds in the residues are broken with a formation of Ni3Fe, Fe, and free carbon with a small admixture of nitrogen. Elementary carbon can be easily separated from metals by treatment with a water solution of hydrochloric acid. Only carbon is responsible for the specific surface of the composite products. The released carbon has a high degree of graphitization and begins to oxidize in air above 500 degrees C and is completely oxidized above 700 degrees C.
引用
收藏
页数：11
相关论文
共 50 条
  • [41] AN ADIABATIC CALORIMETRY STUDY OF [NI(NH3)6](NO3)2
    MIGDALMIKULI, A
    MIKULI, E
    RACHWALSKA, M
    STANEK, T
    JANIK, JM
    JANIK, JA
    PHYSICA B & C, 1981, 104 (03): : 331 - 336
  • [42] Thermal decomposition of polycrystalline [Ni(NH3)6](NO3)2
    Mikuli, Edward
    Migdal-Mikuli, Anna
    Majda, Dorota
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 112 (03) : 1191 - 1198
  • [43] Thermal decomposition of polycrystalline [Ni(NH3)6](NO3)2
    Edward Mikuli
    Anna Migdał-Mikuli
    Dorota Majda
    Journal of Thermal Analysis and Calorimetry, 2013, 112 : 1191 - 1198
  • [44] PHASE-TRANSITIONS IN [NI(NH3)6](NO3)2
    TRYBULA, Z
    STANKOWSKI, J
    PHYSICA B, 1988, 154 (01): : 87 - 92
  • [45] ELECTRICAL-RESISTIVITY OF SOLID CA(NH3)6, SR(NH3)6 AND BA(NH3)6
    MOBLEY, MJ
    GLAUNSINGER, WS
    THOMPSON, JC
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1979, 24 (03): : 409 - 409
  • [46] ESR OF CU2+ IN CD(NH3)2.NI(CN)4.2C6H6
    NAGATA, S
    MIYAKO, Y
    WATANABE, T
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1973, 34 (05) : 1158 - 1162
  • [47] ANALYSIS OF THE DISORDERED ORIENTATION OF NO3- AND BF4- MOLECULES IN [NI(NH3)6](NO3)2 AND [NI(NH3)6](BF4)2
    HOSER, A
    VOGT, K
    PRANDL, W
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1983, 162 (1-4): : 112 - 113
  • [48] CO2 Hydrogenation over Fe-Co Bimetallic Catalyst Derived from the Thermolysis of [Co(NH3)6][Fe(CN)6]
    Gosteva, Alevtina N.
    Kulikova, Mayya V.
    Ivantsov, Mikhail I.
    Grabchak, Alena A.
    Semushina, Yulya P.
    Lapuk, Semen E.
    Gerasimov, Alexander V.
    Tsvetov, Nikita S.
    CATALYSTS, 2023, 13 (12)
  • [49] Metal-carbon compositions as thermolysis products of complex compounds [Co(A)6]X[Fe(CN)6]y•nH2O (A = NH3, en/2)
    Pechenyuk, S., I
    Domonov, D. P.
    Semushina, Yu P.
    Tsvetov, N. S.
    Kadyrova, G., I
    Belyaevskii, A. T.
    THERMOCHIMICA ACTA, 2021, 703
  • [50] THE EFFECTS OF NH3 FREE ROTATION ON THE INELASTIC NEUTRON-SCATTERING SPECTRUM OF NI(NH3)2NI(CN)4.2C6D6 AT 20-K
    KEARLEY, GJ
    CODDENS, G
    FILLAUX, F
    TOMKINSON, J
    WEGENER, W
    CHEMICAL PHYSICS, 1993, 176 (01) : 279 - 287
12345