Formation of Nanostructured Carbon from [Ni(NH3)6]3[Fe(CN)6]2

被引：7

作者：

Domonov, Denis P. ^{[1
]}

Pechenyuk, Sophiya I. ^{[1
]}

Belyaevskii, Alexander T. ^{[1
]}

Yusenko, Kirill V. ^{[2
]}

机构：

[1] RAS, KSC ICTREMR, Tananaev Inst Chem & Technol Rare Elements & Mine, Akad Rodok 26a, Apatity 184209, Murmansk Region, Russia

[2] Bundesanstalt Mat Forsch & Prufung BAM, Richard Willstatter Str 11, D-12489 Berlin, Germany

来源：

NANOMATERIALS | 2020年 / 10卷 / 02期

关键词：

double complex compound; thermal decomposition; carbon materials; MICROSTRUCTURAL CHANGES; HEXACYANOFERRATE(III); COMPLEXES; THERMOLYSIS; PRECURSORS; SYSTEM; METAL;

D O I：

10.3390/nano10020389

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The products of thermal decomposition in an argon atmosphere of [Ni(NH3)(6)](3)[Fe(CN)(6)](2) as a precursor has been studied. Decomposition products were studied up to 800 degrees C. Above 600 degrees C, all coordination bonds in the residues are broken with a formation of Ni3Fe, Fe, and free carbon with a small admixture of nitrogen. Elementary carbon can be easily separated from metals by treatment with a water solution of hydrochloric acid. Only carbon is responsible for the specific surface of the composite products. The released carbon has a high degree of graphitization and begins to oxidize in air above 500 degrees C and is completely oxidized above 700 degrees C.

引用

页数：11

共 50 条

[31] MAGNETIC INVESTIGATION OF SINGLE CRYSTAL OF NI(NH3)2.NI(CN)4.2C6H6
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