A novel palladium-catalyzed synthesis of β-carbolines:: application in total synthesis of naturally occurring alkaloids

被引：48
|
作者：
Dantale, SW [1 ]
Söderberg, BCG [1 ]
机构：
[1] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA
来源：
TETRAHEDRON | 2003年 / 59卷 / 29期
关键词：
palladium; catalysis; alkaloids; carboline;
D O I：
10.1016/S0040-4020(03)00824-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two naturally occurring beta-carbolines, 6-methoxy-2-methyl-1,2,3,4-tetrahydro-beta-carboline and bauerine A, have been prepared using a Stille-type coupling, followed by a palladium-phosphine catalyzed N-heteroannulation as the key steps. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：5507 / 5514
页数：8
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