Rapid Photochemical Reaction Studies under Continuous-flow Conditions in the Vapourtec UV-150 Reactor - A Technical Note

被引：5

作者：

Hunter, Richard ^{[1
]}

Josland, Sam ^{[1
]}

Moore, Joseph ^{[2
]}

Guthrie, Duncan ^{[2
]}

Robertson, Mark J. ^{[1
]}

Oelgemoeller, Michael ^{[1
]}

机构：

[1] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4911, Australia

[2] Vapourtec Ltd, Pk Farm Business Ctr,Fornham St Genevieve, Bury St Edmunds IP28 6TS, Suffolk, England

来源：

CURRENT ORGANIC CHEMISTRY | 2018年 / 22卷 / 25期

基金：

澳大利亚研究理事会;

关键词：

Photochemistry; flow chemistry; capillary reactor; photodecarboxylation; photocycloaddition; TiO2; photocatalysis; photooxy-genation; PHOTODECARBOXYLATIVE BENZYLATIONS; SINGLET OXYGEN; MASS-TRANSFER; LIGHT; MICROPHOTOCHEMISTRY; CARBOXYLATES; BATCH; PHOTOOXYGENATIONS; PHOTOCATALYSIS; PHTHALIMIDES;

D O I：

10.2174/1385272822666181109103342

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Five different model reactions (photodecarboxylation, inter- and intramolecular [2+2] cycloadditions, TiO2 photocatalytic reduction and type II photooxygenation) were investigated in the advanced Vapourtec UV-150 photo reactor with their conversion and throughput potentials reported. Compared to known batch reactions in laboratory reactors, significantly higher calculated productivities were achieved despite a rather small 10 mL reactor coil. The device enables rapid, convenient, reliable and reproducible flow photo-chemistry studies across the entire wavelengths spectrum and on flexible scales.

引用

页码：2501 / 2508

页数：8

共 32 条

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