Rapid Photochemical Reaction Studies under Continuous-flow Conditions in the Vapourtec UV-150 Reactor - A Technical Note

被引：5
|
作者：
Hunter, Richard [1 ]
Josland, Sam [1 ]
Moore, Joseph [2 ]
Guthrie, Duncan [2 ]
Robertson, Mark J. [1 ]
Oelgemoeller, Michael [1 ]
机构：
[1] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4911, Australia
[2] Vapourtec Ltd, Pk Farm Business Ctr,Fornham St Genevieve, Bury St Edmunds IP28 6TS, Suffolk, England
来源：
CURRENT ORGANIC CHEMISTRY | 2018年 / 22卷 / 25期
基金：
澳大利亚研究理事会;
关键词：
Photochemistry; flow chemistry; capillary reactor; photodecarboxylation; photocycloaddition; TiO2; photocatalysis; photooxy-genation; PHOTODECARBOXYLATIVE BENZYLATIONS; SINGLET OXYGEN; MASS-TRANSFER; LIGHT; MICROPHOTOCHEMISTRY; CARBOXYLATES; BATCH; PHOTOOXYGENATIONS; PHOTOCATALYSIS; PHTHALIMIDES;
D O I：
10.2174/1385272822666181109103342
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Five different model reactions (photodecarboxylation, inter- and intramolecular [2+2] cycloadditions, TiO2 photocatalytic reduction and type II photooxygenation) were investigated in the advanced Vapourtec UV-150 photo reactor with their conversion and throughput potentials reported. Compared to known batch reactions in laboratory reactors, significantly higher calculated productivities were achieved despite a rather small 10 mL reactor coil. The device enables rapid, convenient, reliable and reproducible flow photo-chemistry studies across the entire wavelengths spectrum and on flexible scales.
引用
收藏
页码：2501 / 2508
页数：8
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