Honeycomb reactor: a promising device for streamlining aerobic oxidation under continuous-flow conditions

被引：2

作者：

Hosoya, Masahiro ^{[1
]}

Saito, Yusuke ^{[2
]}

Horiuchi, Yousuke ^{[2
]}

机构：

[1] Shionogi & Co Ltd, API R&D Lab, Res Div, 1-1 Futaba Cho 3 Chome, Toyonaka, Osaka 5610825, Japan

[2] Cataler Corp, Carbon Neutral Promot Div, ARK Creat Ctr, 1905-10 Shimonobe, Iwata, Shizuoka 4380112, Japan

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 19卷

关键词：

aerobic oxidation; benzaldehydes; benzyl alcohols; homogeneous catalyst; honeycomb reactor; SELECTIVE OXIDATION; ALCOHOL OXIDATION; MOLECULAR-OXYGEN; CATALYST; ORGANOCATALYST; MICROMIXERS; TEMPO;

D O I：

10.3762/bjoc.19.55

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report on the high potential of a honeycomb reactor for the use in aerobic oxidation under continuous-flow conditions. The honeycomb reactor is made of porous material with narrow channels separated by porous walls allowing for high density accumulation in the reactor. This structure raised the mixing efficiency of a gas-liquid reaction system, and it effectively accelerated the aerobic oxidation of benzyl alcohols to benzaldehydes under continuous-flow conditions. This reactor is a promising device for streamlining aerobic oxidation with high process safety because it is a closed system.

引用

页码：752 / 763

页数：12

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