A highly active and reusable copper(I)-tren catalyst for the "click'' 1,3-dipolar cycloaddition of azides and alkynes

被引:209
|
作者
Candelon, Nicolas [1 ]
Lastecoueres, Dominique [1 ]
Diallo, Abdou Khadri [1 ]
Aranzaes, Jaime Ruiz [1 ]
Astruc, Didier [1 ]
Vincent, Jean-Marc [1 ]
机构
[1] Univ Bordeaux 1, Inst Mol Sci, CNRS, UMR 5255, F-33405 Talence, France
关键词
D O I
10.1039/b716306a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The copper(I) complex [Cu(C18(6)tren)] Br 1 (C18(6)tren = tris(2-dioctadecylaminoethyl) amine) which exhibits a good stability towards aerobic conditions is a versatile, highly reactive and recyclable catalyst for the Huisgen cycloaddition of azides with terminal or internal alkynes and is a useful catalyst for the preparation of "click'' dendrimers.
引用
收藏
页码:741 / 743
页数:3
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