A highly active and reusable copper(I)-tren catalyst for the "click'' 1,3-dipolar cycloaddition of azides and alkynes

被引：209
|
作者：
Candelon, Nicolas [1 ]
Lastecoueres, Dominique [1 ]
Diallo, Abdou Khadri [1 ]
Aranzaes, Jaime Ruiz [1 ]
Astruc, Didier [1 ]
Vincent, Jean-Marc [1 ]
机构：
[1] Univ Bordeaux 1, Inst Mol Sci, CNRS, UMR 5255, F-33405 Talence, France
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 06期
关键词：
D O I：
10.1039/b716306a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The copper(I) complex [Cu(C18(6)tren)] Br 1 (C18(6)tren = tris(2-dioctadecylaminoethyl) amine) which exhibits a good stability towards aerobic conditions is a versatile, highly reactive and recyclable catalyst for the Huisgen cycloaddition of azides with terminal or internal alkynes and is a useful catalyst for the preparation of "click'' dendrimers.
引用
收藏
页码：741 / 743
页数：3
相关论文
共 50 条
  • [31] Synthesis of [(Arylselanyl)alkyl]-1,2,3-triazoles by Copper-Catalyzed 1,3-Dipolar Cycloaddition of (Arylselanyl)alkynes with Benzyl Azides
    Saraiva, Maiara T.
    Seus, Natalia
    de Souza, Diego
    Rodrigues, Oscar E. D.
    Paixao, Marcio W.
    Jacob, Raquel G.
    Lenardao, Eder J.
    Perin, Gelson
    Alves, Diego
    SYNTHESIS-STUTTGART, 2012, 44 (13): : 1997 - 2004
  • [32] Elusive ethynyl azides: trapping by 1,3-dipolar cycloaddition and decomposition to cyanocarbenes
    Banert, Klaus
    Hagedorn, Manfred
    Wutke, Jens
    Ecorchard, Petra
    Schaarschmidt, Dieter
    Lang, Heinrich
    CHEMICAL COMMUNICATIONS, 2010, 46 (23) : 4058 - 4060
  • [33] Organocatalytic 1,3-dipolar cycloaddition reactions of ketones and azides with water as a solvent
    Yeung, Dwun Kit Jonathan
    Gao, Tao
    Huang, Jiayao
    Sun, Shaofa
    Guo, Haibing
    Wang, Jian
    GREEN CHEMISTRY, 2013, 15 (09) : 2384 - 2388
  • [34] 1,3-dipolar cycloaddition reactions of substituted benzyl azides with acetylenic compounds
    Abu-Orabi, ST
    MOLECULES, 2002, 7 (02) : 302 - 314
  • [35] (Iminophosphorane)copper(I) Complexes as Highly Efficient Catalysts for 1,3-Dipolar Cycloaddition of Azides with Terminal and 1-Iodoalkynes in Water: One-Pot Multi-Component Reaction from Alkynes and in situ Generated Azides
    Garcia-Alvarez, Joaquin
    Diez, Josefina
    Gimeno, Jose
    Suarez, Francisco J.
    Vincent, Cristian
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (35) : 5854 - 5863
  • [36] Strain-Promoted 1,3-Dipolar Cycloaddition of Cycloalkynes and Organic Azides
    Jan Dommerholt
    Floris P. J. T. Rutjes
    Floris L. van Delft
    Topics in Current Chemistry, 2016, 374
  • [37] Strain-Promoted 1,3-Dipolar Cycloaddition of Cycloalkynes and Organic Azides
    Dommerholt, Jan
    Rutjes, Floris P. J. T.
    van Delft, Floris L.
    TOPICS IN CURRENT CHEMISTRY, 2016, 374 (02)
  • [38] REACTIVITY OF SUBSTITUTED NORBORNENES IN 1,3-DIPOLAR CYCLOADDITION REACTION WITH ARYL AZIDES
    SAMUILOV, YD
    MOVCHAN, AI
    KONOSHENKO, LV
    PLEMENKOV, VV
    KONOVALOV, AI
    ZHURNAL ORGANICHESKOI KHIMII, 1981, 17 (08): : 1626 - 1629
  • [39] Highly enantioselective asymmetric 1,3-dipolar cycloaddition of azomethine ylide catalyzed by a copper(I)/ClickFerrophos complex
    Fukuzawa, Shin-ichi
    Oki, Hiroshi
    ORGANIC LETTERS, 2008, 10 (09) : 1747 - 1750
  • [40] 1,3-dipolar cycloaddition: Click chemistry for the synthesis of 5-substituted tetrazoles from organoaluminum azides and nitriles
    Aureggi, Valentina
    Sedelmeier, Gottfried
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (44) : 8440 - 8444
12345