Solvent effects on the redox potentials of ferrocene and methylferrocenes

被引:0
|
作者
Makitra, RG [1 ]
Prystansky, RE [1 ]
机构
[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, Dept Fossil Fuel Phys Chem & Engn, UA-79060 Lvov, Ukraine
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The redox potentials of ferrocene and pentamethylferrocene are correlated with the physicochemical properties of solvents using linear multiparameter equations. Of greatest significance is the specific solvating ability of the solvents. This approach is inapplicable to decamethylferrocene because of its more complicated mechanism of solvation.
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页码:101 / 106
页数:6
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