Synthesis, characterization and computational studies of luminescent rhenium(I) tricarbonyl diimine complexes with 8-hydroxyquinoline-containing alkynyl ligands

被引：11

作者：

Chung, Wai-Kin

Maggie Ng

Zhu, Nianyong

Siu, Steven Kin-Lok

Yam, Vivian Wing-Wah ^{[1
]}

机构：

[1] Univ Hong Kong, Univ Grants Comm Hong Kong, Areas Excellence Scheme, Inst Mol Funct Mat, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 847卷

关键词：

Electrochemistry; Luminescence; Metal alkynyl; Rhenium(I) diimine; UV-vis absorption; X-RAY CRYSTAL; MOLECULAR-ORBITAL METHODS; HYDROCARBON-BRIDGED COMPLEXES; TRANSITION-METAL-COMPLEXES; EXCITED-STATE; COORDINATED CARBON; BASIS-SETS; STRUCTURAL-CHARACTERIZATION; ELECTROCATALYTIC REDUCTION; POLARIZATION FUNCTIONS;

D O I：

10.1016/j.jorganchem.2017.04.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of 8-hydroxyquinoline-containing alkynylrhenium(I) tricarbonyl diimine complexes has been designed and synthesized. Their UV-vis absorption, emission as well as electrochemical properties have been studied. Computational studies have also been performed to provide insights into the electronic transitions, excited state origins and electrochemical properties of the complexes. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：278 / 288

页数：11

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