Synthesis, characterization and computational studies of luminescent rhenium(I) tricarbonyl diimine complexes with 8-hydroxyquinoline-containing alkynyl ligands

被引:11
|
作者
Chung, Wai-Kin
Maggie Ng
Zhu, Nianyong
Siu, Steven Kin-Lok
Yam, Vivian Wing-Wah [1 ]
机构
[1] Univ Hong Kong, Univ Grants Comm Hong Kong, Areas Excellence Scheme, Inst Mol Funct Mat, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China
关键词
Electrochemistry; Luminescence; Metal alkynyl; Rhenium(I) diimine; UV-vis absorption; X-RAY CRYSTAL; MOLECULAR-ORBITAL METHODS; HYDROCARBON-BRIDGED COMPLEXES; TRANSITION-METAL-COMPLEXES; EXCITED-STATE; COORDINATED CARBON; BASIS-SETS; STRUCTURAL-CHARACTERIZATION; ELECTROCATALYTIC REDUCTION; POLARIZATION FUNCTIONS;
D O I
10.1016/j.jorganchem.2017.04.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of 8-hydroxyquinoline-containing alkynylrhenium(I) tricarbonyl diimine complexes has been designed and synthesized. Their UV-vis absorption, emission as well as electrochemical properties have been studied. Computational studies have also been performed to provide insights into the electronic transitions, excited state origins and electrochemical properties of the complexes. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:278 / 288
页数:11
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