Synthesis, characterization and computational studies of luminescent rhenium(I) tricarbonyl diimine complexes with 8-hydroxyquinoline-containing alkynyl ligands

被引：11
|
作者：
Chung, Wai-Kin
Maggie Ng
Zhu, Nianyong
Siu, Steven Kin-Lok
Yam, Vivian Wing-Wah [1 ]
机构：
[1] Univ Hong Kong, Univ Grants Comm Hong Kong, Areas Excellence Scheme, Inst Mol Funct Mat, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 847卷
关键词：
Electrochemistry; Luminescence; Metal alkynyl; Rhenium(I) diimine; UV-vis absorption; X-RAY CRYSTAL; MOLECULAR-ORBITAL METHODS; HYDROCARBON-BRIDGED COMPLEXES; TRANSITION-METAL-COMPLEXES; EXCITED-STATE; COORDINATED CARBON; BASIS-SETS; STRUCTURAL-CHARACTERIZATION; ELECTROCATALYTIC REDUCTION; POLARIZATION FUNCTIONS;
D O I：
10.1016/j.jorganchem.2017.04.016
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of 8-hydroxyquinoline-containing alkynylrhenium(I) tricarbonyl diimine complexes has been designed and synthesized. Their UV-vis absorption, emission as well as electrochemical properties have been studied. Computational studies have also been performed to provide insights into the electronic transitions, excited state origins and electrochemical properties of the complexes. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：278 / 288
页数：11
相关论文
共 50 条
  • [1] Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands
    Lam, Siu-Tung
    Zhu, Nianyong
    Au, Vonika Ka-Man
    Yam, Vivian Wing-Wah
    [J]. POLYHEDRON, 2015, 86 : 10 - 16
  • [2] Synthesis, characterisation and photophysical studies of leucotriarylmethanes-containing ligands and their rhenium(I) tricarbonyl diimine complexes
    Ko, Chi-Chiu
    Ng, Chi-On
    Feng, Hua
    Chu, Wing-Kin
    [J]. DALTON TRANSACTIONS, 2010, 39 (28) : 6475 - 6482
  • [3] Luminescent rhenium(I) tricarbonyl complexes with pyrazolylamidino ligands: photophysical, electrochemical, and computational studies
    Gomez-Iglesias, Patricia
    Guyon, Fabrice
    Khatyr, Abderrahim
    Ulrich, Gilles
    Knorr, Michael
    Miguel Martin-Alvarez, Jose
    Miguel, Daniel
    Villafane, Fernando
    [J]. DALTON TRANSACTIONS, 2015, 44 (40) : 17516 - 17528
  • [4] Synthesis, characterization, and fluorescence and cytotoxicity studies of (tricarbonyl)rhenium(I) (diimine) complexes containing N-protected amino acid ligands
    Orsa, Dejene K.
    Iwunze, Maurice O.
    Pramanik, Saroj K.
    Greco, George E.
    Mandal, Santosh K.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [5] Synthesis, characterization, photophysical, and computational studies of Rhenium(I) tricarbonyl complexes containing the derivatives of bipyrazine
    Kirgan, Robert
    Simpson, Megan
    Moore, Curtis
    Day, Jeff
    Bui, Loan
    Tanner, Clayton
    Rillema, D. Paul
    [J]. INORGANIC CHEMISTRY, 2007, 46 (16) : 6464 - 6472
  • [6] Synthesis, characterization, and fluorescence and cytotoxicity studies of rhenium(I) (tricarbonyl)(α-diimine) pentylcarbonato complexes
    Powell, Brent V.
    Mandal, Santosh
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [7] Syntheses, photophysical, electroluminescence and computational studies of rhenium(I) diimine triarylamine-containing alkynyl complexes
    Chung, Wai-Kin
    Wong, Keith Man-Chung
    Lam, Wai Han
    Zhu, Xiuling
    Zhu, Nianyong
    Kwok, Hoi-Sing
    Yam, Vivian Wing-Wah
    [J]. NEW JOURNAL OF CHEMISTRY, 2013, 37 (06) : 1753 - 1767
  • [8] Protein binding studies of luminescent rhenium(I) diimine complexes
    Bhuvaneswari, Jayaraman
    Mareeswaran, Paulpandian Muthu
    Shanmugasundaram, Sambandam
    Rajagopal, Seenivasan
    [J]. INORGANICA CHIMICA ACTA, 2011, 375 (01) : 205 - 212
  • [9] Synthesis and Characterization of Luminescent Rhenium(I) Tricarbonyl Diimine Complexes with a Triarylboron Moiety and the Study of Their Fluoride Ion-Binding Properties
    Lam, Siu-Tung
    Zhu, Nianyong
    Yam, Vivian Wing-Wah
    [J]. INORGANIC CHEMISTRY, 2009, 48 (20) : 9664 - 9670
  • [10] Synthesis, spectral and structural characterization and computational studies of rhenium(I)-tricarbonyl nitrito complexes of 2,2′-bipyridine and 2,9-dimethylphenanthroline ligands: π-Accepting character of the diimine ligands
    Kia, Reza
    Safari, Fatemeh
    [J]. INORGANICA CHIMICA ACTA, 2016, 453 : 357 - 368
12345