Electron-transfer induced isomerizations of coordination compounds

被引：81
|
作者：
Pombeiro, AJL [1 ]
da Silva, MFCG [1 ]
Lemos, MANDA [1 ]
机构：
[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 219卷
关键词：
molecular electrochemistry; redox processes; electron-transfer; isomerization; mechanisms; octahedral complexes;
D O I：
10.1016/S0010-8545(01)00299-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Geometrical isomerization processes induced electrochemically are reviewed for octahedral-type complexes, in particular with pi -electron acceptor ligands, with focus on those whose mechanisms have been established in terms of square ECEC-type schemes and electron-transfer chain catalysis. Rationalizations based on the isomeric redox potential differentiation are also presented. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
下载
收藏
页码：53 / 80
页数：28
相关论文
共 50 条
12345