Electron-transfer induced isomerizations of coordination compounds

被引：81

作者：

Pombeiro, AJL ^{[1
]}

da Silva, MFCG ^{[1
]}

Lemos, MANDA ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 219卷

关键词：

molecular electrochemistry; redox processes; electron-transfer; isomerization; mechanisms; octahedral complexes;

D O I：

10.1016/S0010-8545(01)00299-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Geometrical isomerization processes induced electrochemically are reviewed for octahedral-type complexes, in particular with pi -electron acceptor ligands, with focus on those whose mechanisms have been established in terms of square ECEC-type schemes and electron-transfer chain catalysis. Rationalizations based on the isomeric redox potential differentiation are also presented. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：53 / 80

页数：28

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