New type of trivalent gadolinium ion conducting solid electrolyte

被引：0

作者：

Tamura, S. ^{[1
]}

Yamamoto, S. ^{[1
]}

Imanaka, N. ^{[1
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS | 2008年 / 11卷 / 01期

关键词：

solid electrolyte; NASICON type; trivalent ion; gadolinium;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new type of Gd3+ ion conducting solid electrolyte, Gd(1+x)/3Zr2P3-xSixO12 (0.0 <= x <= 0.3), with the NASICON type structure, was developed and their ion conducting properties were investigated. Among the samples prepared, Gd1.1/3Zr2P2.9Si0.1O12 (X = 0.1) possessed the largest crystal lattice size, resulting in showing the highest ion conductivity of 3.41 x 10(-5) S.cm(-1) at 600 degrees C. Predominant conducting species in the Gd1.1/3Zr2P2.9Si0.1O12 solid was successfully demonstrated to be Gd3+ ion by the dc polarization measurement and the dc electrolysis method.

引用

页码：1 / 4

页数：4

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