Complexes of some 3d metal ions of the Schiff's base, N,N′-di-4-(4′-pentyloxybenzoate) salicylidene-1", 3"-diamino-2"-propanol: Synthesis and spectral studies

被引：4
|
作者：
Singh, Angad Kumar [1 ]
Kumari, Sanyucta [1 ]
Shakya, Pawan Raj [1 ]
Rao, T. R. [1 ]
机构：
[1] Banaras Hindu Univ, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS | 2011年 / 31卷 / 05期
关键词：
Nematogenic; Schiff's base; Metallomesogens; Square-pyramidal; NMR and IR spectra; ELECTRON-SPIN-RESONANCE; MESOMORPHIC PROPERTIES; CRYSTAL-STRUCTURE; COORDINATION-COMPOUNDS; COPPER(II) COMPLEXES; ZN(II) COMPLEX; DERIVATIVES; METALLOMESOGENS; NICKEL(II); COBALT(II);
D O I：
10.1016/j.msec.2011.04.006
中图分类号：
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号：
0805 ; 080501 ; 080502 ;
摘要：
A nematogenic Schiff's base, N,N'-di-4-(4'-pentyloxybenzoate)salicylidene-1 '', 3 ''-diamino-2 ''-propanol, (abbreviated as H(2)L(6)), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in its metal complexes of the general formula, [ML(6)](n) where M(Ji) Mn, Co, Ni, Cu and Zn. Their structural characterizations were made by various spectroscopic techniques. (C) 2011 Elsevier B.V. All rights reserved.
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页码：1111 / 1114
页数：4
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