Complexes of some 3d metal ions of the Schiff's base, N,N′-di-4-(4′-pentyloxybenzoate) salicylidene-1", 3"-diamino-2"-propanol: Synthesis and spectral studies

被引：4

作者：

Singh, Angad Kumar ^{[1
]}

Kumari, Sanyucta ^{[1
]}

Shakya, Pawan Raj ^{[1
]}

Rao, T. R. ^{[1
]}

机构：

[1] Banaras Hindu Univ, Dept Chem, Varanasi 221005, Uttar Pradesh, India

来源：

MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS | 2011年 / 31卷 / 05期

关键词：

Nematogenic; Schiff's base; Metallomesogens; Square-pyramidal; NMR and IR spectra; ELECTRON-SPIN-RESONANCE; MESOMORPHIC PROPERTIES; CRYSTAL-STRUCTURE; COORDINATION-COMPOUNDS; COPPER(II) COMPLEXES; ZN(II) COMPLEX; DERIVATIVES; METALLOMESOGENS; NICKEL(II); COBALT(II);

D O I：

10.1016/j.msec.2011.04.006

中图分类号：

TB3 [工程材料学]; R318.08 [生物材料学];

学科分类号：

0805 ; 080501 ; 080502 ;

摘要：

A nematogenic Schiff's base, N,N'-di-4-(4'-pentyloxybenzoate)salicylidene-1 '', 3 ''-diamino-2 ''-propanol, (abbreviated as H(2)L(6)), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in its metal complexes of the general formula, [ML(6)](n) where M(Ji) Mn, Co, Ni, Cu and Zn. Their structural characterizations were made by various spectroscopic techniques. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1111 / 1114

页数：4

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