HIGHLY ENANTIOSELECTIVE OXIDATION OF ARYL BENZYL SULFIDES

被引：3
|
作者：
Cardellicchio, Cosimo [1 ]
Capozzi, Maria Annunziata M. [2 ]
Centrone, Caterina
Naso, Francesco
机构：
[1] Univ Bari, CNR ICCOM, Dipartimento Chim, I-70125 Bari, Italy
[2] Univ Foggia, Dipartimento Sci Agroambientali Chim & Difesa Veg, Foggia, Italy
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2011年 / 186卷 / 05期
关键词：
Hydrobenzoin; oxidation mechanism; sulfoxide; titanium complex; CARBON SUBSTITUTION-REACTIONS; DIALKYL SULFOXIDES; SULFINYL GROUP; LEAVING GROUPS; ROUTE;
D O I：
10.1080/10426507.2010.529856
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Enantiopure aryl benzyl sulfoxides were easily obtained by an enantioselective oxidation of the corresponding sulfides with tert-butyl hydroperoxide in the presence of a complex between titanium and (S, S)- or (R, R)-hydrobenzoin. Theoretical and experimental investigations confirmed that these aryl benzyl sulfides represent an ideal substrate for the asymmetric oxidation system.
引用
收藏
页码：1193 / 1195
页数：3
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