HIGHLY ENANTIOSELECTIVE OXIDATION OF ARYL BENZYL SULFIDES

被引：3

作者：

Cardellicchio, Cosimo ^{[1
]}

Capozzi, Maria Annunziata M. ^{[2
]}

Centrone, Caterina

Naso, Francesco

机构：

[1] Univ Bari, CNR ICCOM, Dipartimento Chim, I-70125 Bari, Italy

[2] Univ Foggia, Dipartimento Sci Agroambientali Chim & Difesa Veg, Foggia, Italy

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2011年 / 186卷 / 05期

关键词：

Hydrobenzoin; oxidation mechanism; sulfoxide; titanium complex; CARBON SUBSTITUTION-REACTIONS; DIALKYL SULFOXIDES; SULFINYL GROUP; LEAVING GROUPS; ROUTE;

D O I：

10.1080/10426507.2010.529856

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiopure aryl benzyl sulfoxides were easily obtained by an enantioselective oxidation of the corresponding sulfides with tert-butyl hydroperoxide in the presence of a complex between titanium and (S, S)- or (R, R)-hydrobenzoin. Theoretical and experimental investigations confirmed that these aryl benzyl sulfides represent an ideal substrate for the asymmetric oxidation system.

引用

页码：1193 / 1195

页数：3

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