A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition

被引：20
|
作者：
Lee, Way-Zen [1 ]
Wang, Tzu-Li
Chang, Hao-Ching
Chen, Yi-Ting
Kuo, Ting-Shen [1 ]
机构：
[1] Natl Taiwan Normal Univ, Dept Chem, Instrumentat Ctr, Taipei 11650, Taiwan
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 11期
关键词：
PURPLE ACID-PHOSPHATASE; ASYMMETRIC CONJUGATE ADDITION; NITROALDOL REACTIONS; MOLECULAR-OXYGEN; THIOLATE ANIONS; BASE COMPLEX; OXIDATION; BOND; REACTIVITY; LIGAND;
D O I：
10.1021/om300275a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel tetranuclear Zn-II/Fe-III heterobimetallic complex was synthesized, and the complex can efficiently catalyze the Michael addition of thiophenols to alpha,beta-unsaturated enones, even for tertiary carbon sulfur bond formation.
引用
收藏
页码：4106 / 4109
页数：4
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