A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition

被引：20
|
作者：
Lee, Way-Zen [1 ]
Wang, Tzu-Li
Chang, Hao-Ching
Chen, Yi-Ting
Kuo, Ting-Shen [1 ]
机构：
[1] Natl Taiwan Normal Univ, Dept Chem, Instrumentat Ctr, Taipei 11650, Taiwan
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 11期
关键词：
PURPLE ACID-PHOSPHATASE; ASYMMETRIC CONJUGATE ADDITION; NITROALDOL REACTIONS; MOLECULAR-OXYGEN; THIOLATE ANIONS; BASE COMPLEX; OXIDATION; BOND; REACTIVITY; LIGAND;
D O I：
10.1021/om300275a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel tetranuclear Zn-II/Fe-III heterobimetallic complex was synthesized, and the complex can efficiently catalyze the Michael addition of thiophenols to alpha,beta-unsaturated enones, even for tertiary carbon sulfur bond formation.
引用
收藏
页码：4106 / 4109
页数：4
相关论文
共 50 条
  • [21] A Twist on Controlling the Equilibrium of Dynamic Thia-Michael Reactions
    Crolais, Alex E.
    Chen, Chuqiao
    Gao, Junhao
    Dolinski, Neil D.
    Xu, Yinan
    de Pablo, Juan J.
    Snyder, Scott A.
    Rowan, Stuart J.
    JOURNAL OF ORGANIC CHEMISTRY, 2025,
  • [22] A solvent-dependent chirality-switchable thia-Michael addition to α,β-unsaturated carboxylic acids using a chiral multifunctional thiourea catalyst
    Hayama, Noboru
    Kobayashi, Yusuke
    Sekimoto, Eriko
    Miyazaki, Anna
    Inamoto, Kiyofumi
    Kimachi, Tetsutaro
    Takemoto, Yoshiji
    CHEMICAL SCIENCE, 2020, 11 (21) : 5572 - 5576
  • [23] Fe(OTf)2-Catalyzed Thia-Michael Addition Reaction: A Green Synthetic Approach to -Thioethers
    Lauzon, Samuel
    Li, Mao
    Keipour, Hoda
    Ollevier, Thierry
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (33) : 4536 - 4540
  • [24] Facile synthesis of thiazoles via an intramolecular thia-Michael strategy
    Sasmal, Pradip K.
    Sridhar, S.
    Iqbal, Javed
    TETRAHEDRON LETTERS, 2006, 47 (49) : 8661 - 8665
  • [25] Combination of Fluorine and Tertiary Amine Activation in Catalyst-Free Thia-Michael Covalent Adaptable Networks
    Berne, Dimitri
    Poli, Rinaldo
    Caillol, Sylvain
    Ladmiral, Vincent
    Leclerc, Eric
    MACROMOLECULES, 2023, 56 (20) : 8260 - 8274
  • [26] Boric acid catalyzed thia-Michael reactions in water or alcohols
    Chaudhuri, Mihir K.
    Hussain, Sahid
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 269 (1-2) : 214 - 217
  • [27] A highly efficient, operationally simple and selective thia-Michael addition under solvent-free condition
    Azizi, Najmodin
    Khajeh-Amiri, Alireza
    Ghafuri, Hossein
    Bolourtchian, Mohammad
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2009, 2 (01) : 43 - 46
  • [28] Thia-Michael addition using cheap and odorless S-alkylisothiouronium salts as thiol equivalents in water
    Zhao, Yan
    Ge, Ze-Mei
    Cheng, Tie-Ming
    Li, Run-Tao
    SYNLETT, 2007, (10) : 1529 - 1532
  • [29] One-pot synthesis of poly(vinylidene fluoride) methacrylate macromonomers via thia-Michael addition
    Guerre, Marc
    Ameduri, Bruno
    Ladmiral, Vincent
    POLYMER CHEMISTRY, 2016, 7 (02) : 441 - 450
  • [30] Effect of pH on the Properties of Hydrogels Cross-Linked via Dynamic Thia-Michael Addition Bonds
    FitzSimons, Thomas M.
    Anslyn, Eric, V
    Rosales, Adrianne M.
    ACS POLYMERS AU, 2022, 2 (02): : 129 - 136
12345