Bis(terpyridine)ruthenium(II) bis(hexafluorophosphate) diacetonitrile solvate

被引：59
|
作者：
Lashgari, K [1 ]
Kritikos, M
Norrestam, R
Norrby, T
机构：
[1] Stockholm Univ, Arrhenius Lab, Dept Struct Chem, S-10691 Stockholm, Sweden
[2] Royal Inst Technol, Dept Organ Chem, S-10044 Stockholm, Sweden
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270198011378
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, bis(2,2': 6',2''-terpyridine)ruthenium(II) bis(hexafluorophosphate) diacetonitrile solvate, with the composition [Ru(C15H11N3)(2)](PF6)(2). 2C(2)H(3)N is described. The pseudo-octahedral Ru complex has a C-2 nu point symmetry, imposed by the geometry constraints of the two identical tridentate ligands. The tetragonal unit cell, with its remarkably long c axis [49.306(3)Angstrom], contains two symmetry-independent formula units.
引用
收藏
页码：64 / 67
页数：4
相关论文
共 50 条
  • [41] Towards Larger Polygonal Architectures: Synthesis and Characterization of Iron(II)- and Ruthenium(II)-Bis(terpyridine) Metallomacrocycles
    Chan, Yi-Tsu
    Li, Xiaopeng
    Moorefield, Charles N.
    Wesdemiotis, Chrys
    Newkome, George R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (28) : 7750 - 7754
  • [42] Thermal and Photoinduced Electron Transfer in Directional Bis(terpyridine)ruthenium(II)-(Bipyridine)platinum(II) Complexes
    Dietrich, Jan
    von Leupoldt, Anica Wuensche
    Grabolle, Markus
    Resch-Genger, Ute
    Heinze, Katja
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (17) : 3009 - 3019
  • [43] trans-Bis(O-ethylxanthato)bis(triphenylphosphine)ruthenium(III) hexafluorophosphate monohydrate
    Ohuchi, Y
    Noda, K
    Suzuki, T
    Kashiwabara, K
    Takagi, HD
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1077 - M1078
  • [44] STRUCTURE OF BIS(1,10-PHENANTHROLINE)COPPER(II) BIS(HEXAFLUOROPHOSPHATE)
    AMOURNJARUSIRI, K
    HATHAWAY, BJ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 1383 - 1385
  • [45] Synthesis and Characterization of Extended Bis(terpyridine)ruthenium Amino Acids
    Heinze, Katja
    Hempel, Klaus
    Breivogel, Aaron
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (15): : 2541 - 2549
  • [46] STRUCTURE OF CARBONYLDICHLORO(PARA-CHLOROPHENYL ISOCYANIDE)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) ETHANOL SOLVATE
    CLARK, GR
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (AUG): : 2256 - 2258
  • [47] Efficient N-terminal peptide sequencing using bis(terpyridine)ruthenium(II) derivatives
    Okamura, T
    Ueryama, N
    Iwamura, T
    Ikemori, M
    Kaneko, M
    Masui, K
    Yamamoto, H
    Yamaguchi, M
    Kuyama, H
    Ando, E
    Tsunasawa, S
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 96 (01) : 204 - 204
  • [48] Bis[bis(2-aminoethyl-N)sulfide-S]nickel(II) bis(hexafluorophosphate)
    Blake, AJ
    Danks, JP
    Parsons, S
    Schroder, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 411 - 413
  • [49] [Bis(trispivalatodimolybdenum (II))-μ-bis(4′-carboxylato-2,2′:6′,2″-terpyridine) ruthenium (II)] (2+) Tetrafluoroborate: Photophysical Studies
    Brian G. Alberding
    Malcolm H. Chisholm
    Terry L. Gustafson
    Carly R. Reed
    Namrata Singh
    Claudia Turro
    Journal of Cluster Science, 2009, 20 : 307 - 317
  • [50] Diacetonitrile[N,N′-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]dichloridochromium(II) acetonitrile solvate
    Peitz, Stephan
    Peulecke, Normen
    Mueller, Bernd H.
    Spannenberg, Anke
    Rosenthal, Uwe
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1336 - U867
12345