Bis(terpyridine)ruthenium(II) bis(hexafluorophosphate) diacetonitrile solvate

被引：59
|
作者：
Lashgari, K [1 ]
Kritikos, M
Norrestam, R
Norrby, T
机构：
[1] Stockholm Univ, Arrhenius Lab, Dept Struct Chem, S-10691 Stockholm, Sweden
[2] Royal Inst Technol, Dept Organ Chem, S-10044 Stockholm, Sweden
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270198011378
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, bis(2,2': 6',2''-terpyridine)ruthenium(II) bis(hexafluorophosphate) diacetonitrile solvate, with the composition [Ru(C15H11N3)(2)](PF6)(2). 2C(2)H(3)N is described. The pseudo-octahedral Ru complex has a C-2 nu point symmetry, imposed by the geometry constraints of the two identical tridentate ligands. The tetragonal unit cell, with its remarkably long c axis [49.306(3)Angstrom], contains two symmetry-independent formula units.
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页码：64 / 67
页数：4
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