Syntheses and Structures of Zinc Bis(phosphinimino)methanide Complexes

被引：7

作者：

Bayram, Melike ^{[1
]}

Gondzik, Sebastian ^{[1
]}

Blaeser, Dieter ^{[1
]}

Woelper, Christoph ^{[1
]}

Schulz, Stephan ^{[1
]}

机构：

[1] Univ Duisburg Essen, Inorgan Chem, Univ Str 5-7,S07 S03 C30, D-45117 Essen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 15期

关键词：

Bis(phosphinimino)methanide; Zinc; Single crystal structure; Heteroleptic complex; RING-OPENING POLYMERIZATION; RAY CRYSTAL-STRUCTURES; AMIDINATE COMPLEXES; LANTHANIDE COMPLEXES; COORDINATION SPHERE; MAGNESIUM COMPLEXES; STAUDINGER REACTION; HYDRIDE COMPLEX; LIGANDS; CATALYSIS;

D O I：

10.1002/zaac.201600196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of bis(phosphinimino)methanes H2C(PPh2NR)(2) [R = SiMe3 ((LH)-H-1), Ph ((LH)-H-2), 2,6-iPr(2)-C6H3 (DIPP) ((LH)-H-3)] with ZnR2 (R = Me, Et) yielded the corresponding bis(phosphinimino)methanide zinc complexes LZnMe [L-2 (1), L-3 (2)] and LZnEt [L-1 (3), L-2 (4), and L-3 (5)]. Complexes 1-5 were characterized by heteronuclear NMR (H-1, C-13, P-31) and IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction.

引用

页码：847 / 852

页数：6

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