Syntheses and Structures of Zinc Bis(phosphinimino)methanide Complexes

被引：7

作者：

Bayram, Melike ^{[1
]}

Gondzik, Sebastian ^{[1
]}

Blaeser, Dieter ^{[1
]}

Woelper, Christoph ^{[1
]}

Schulz, Stephan ^{[1
]}

机构：

[1] Univ Duisburg Essen, Inorgan Chem, Univ Str 5-7,S07 S03 C30, D-45117 Essen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 15期

关键词：

Bis(phosphinimino)methanide; Zinc; Single crystal structure; Heteroleptic complex; RING-OPENING POLYMERIZATION; RAY CRYSTAL-STRUCTURES; AMIDINATE COMPLEXES; LANTHANIDE COMPLEXES; COORDINATION SPHERE; MAGNESIUM COMPLEXES; STAUDINGER REACTION; HYDRIDE COMPLEX; LIGANDS; CATALYSIS;

D O I：

10.1002/zaac.201600196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of bis(phosphinimino)methanes H2C(PPh2NR)(2) [R = SiMe3 ((LH)-H-1), Ph ((LH)-H-2), 2,6-iPr(2)-C6H3 (DIPP) ((LH)-H-3)] with ZnR2 (R = Me, Et) yielded the corresponding bis(phosphinimino)methanide zinc complexes LZnMe [L-2 (1), L-3 (2)] and LZnEt [L-1 (3), L-2 (4), and L-3 (5)]. Complexes 1-5 were characterized by heteronuclear NMR (H-1, C-13, P-31) and IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction.

引用

页码：847 / 852

页数：6

共 50 条

[21] A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/hydrosilylation catalysis
Rastätter, M
Zulys, A
Roesky, PW
CHEMICAL COMMUNICATIONS, 2006, (08) : 874 - 876
[22] Syntheses and Structures of Cationic Bis(gold) Cyclopentadienyl Complexes
Slinger, Brady L.
Malek, Jack C.
Widenhoefer, Ross A.
ORGANOMETALLICS, 2024, 44 (01) : 224 - 235
[23] Syntheses and Structures of Bis-Amidinate-Alane Complexes
Bayram, Melike
Blaeser, Dieter
Woelper, Christoph
Schulz, Stephan
ORGANOMETALLICS, 2014, 33 (08) : 2080 - 2087
[24] Syntheses and structures of calcium and ytterbium bis(diphosphanylamido) complexes
Panda, Tarun K.
Gamer, Michael T.
Roesky, Peter W.
INORGANICA CHIMICA ACTA, 2006, 359 (15) : 4765 - 4768
[25] In situ formation of bis(phosphinimino)methanide rare earth alkoxide initiators for the ring-opening polymerization of ε-caprolactone
Gamer, Michael T.
Roesky, Peter W.
Palard, Isabelle
Le Hellaye, Maude
Guillaume, Sophie M.
ORGANOMETALLICS, 2007, 26 (03) : 651 - 657
[26] Syntheses and Structures of Blue Luminescent Zinc(Ⅱ) Complexes with 2,6-Bis(imino)pyridyl Ligands
FAN Rui-qing
Chemical Research in Chinese Universities, 2004, (06) : 801 - 803
[27] Hydrothermal Syntheses,Crystal Structures,and Characterization of Two Zinc(Ⅱ) Complexes Containing Flexible Bis(benzimidazole) Ligands
刘晓兵
张泽婷
王艳彦
刘蕊
赵永
崔广华
结构化学, 2016, 35 (11) : 1745 - 1753
[28] Syntheses and structures of zinc and cadmium iodide complexes with iodoacetamide
Savinkina, Elena V.
Zamilatskov, Ilia A.
Buravlev, Evgeny A.
Albov, Dmitry V.
MENDELEEV COMMUNICATIONS, 2008, 18 (03) : 131 - 132
[29] Yttrium Methanide and Methanediide Bis(silyl)amide Complexes
Ortu, Fabrizio
Gregson, Matthew
Wooles, Ashley J.
Mills, David P.
Liddle, Stephen T.
ORGANOMETALLICS, 2017, 36 (23) : 4584 - 4590
[30] Bis(phosphinimino)methanide borohydride complexes of the rare-earth elements as initiators for the ring-opening polymerization of trimethylene carbonate: combined experimental and computational investigations
Guillaume, Sophie M.
Brignou, Pierre
Susperregui, Nicolas
Maron, Laurent
Kuzdrowska, Magdalena
Kratsch, Jochen
Roesky, Peter W.
POLYMER CHEMISTRY, 2012, 3 (02) : 429 - 435

← 1 2 3 4 5 →