Rubidium and caesium Oxoantimonates(V) with channel structures.: Syntheses, crystal structures and vibrational spectra

被引：0

作者：

Hirschle, C ^{[1
]}

Rosstauscher, J ^{[1
]}

Emmerling, F ^{[1
]}

Röhr, C ^{[1
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2001年 / 56卷 / 02期

关键词：

antimonates(V); oxoantimonates; Raman spectra;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxoantimonates(V) Cs2Sb4O11 (monoclinic, C2/m, a=1964.5(5), b=762.8(2), c=730.2(2) pm, beta =96.276(5)degrees, Z=4) and A(3)Sb(5)O(14) (A=Rb/Cs; orthorhombic, Pbam, a=718.81(9)/ 743.37(13), b=2447.8(2)/2625.1(5), c=733.1(2)/739.6(3) pm, Z=4) were synthesized from Sb2O5 and the peroxides AO(2) (A=Rb, CS). Their crystal structures were determined on the basis of single crystal diffractometer data. The structures are composed of three-dimensional nets of [SbO6] octahedra connected via common corners and edges, with the A cations incorporated in the resulting channel systems. The Raman spectra of the compounds are discussed in relation with the different type of oxide connectivites in the oxoantimonate anions.

引用

页码：169 / 178

页数：10

共 50 条

[31] Syntheses, single-crystal structures, vibrational spectra and DSC/TG analyses of orthorhombic and trigonal Ag[N(CN)2]
Reckeweg, Olaf
Schulz, Armin
Schneck, Christof
Lissner, Falk
Schleid, Thomas
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2016, 71 (07): : 827 - 834
[32] Vibrational spectra of aluminosilicate ring structures
Mozgawa, W
Sitarz, M
JOURNAL OF MOLECULAR STRUCTURE, 2002, 614 (1-3) : 273 - 279
[33] VIBRATIONAL-SPECTRA AND STRUCTURES OF ACYLPHOSPHINES
RAZUMOVA, ER
ELNATANOV, YI
SHIKHALIEV, SM
KOSTYANOVSKII, RG
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1978, 27 (01): : 85 - 90
[34] STRUCTURES AND VIBRATIONAL SPECTRA OF TRIMETHOXYMETHANE AND TETRAMETHOXYMETHANE
LEE, H
WILMSHUR.JK
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (02): : 347 - &
[35] Syntheses, crystal structures, and CD spectra of simple heterobimetallic transition metal binaphtholates
Cross, RJ
Farrugia, LC
McArthur, DR
Peacock, RD
Taylor, DSC
INORGANIC CHEMISTRY, 1999, 38 (25) : 5698 - 5702
[36] Synthesis, characterization, and crystal and molecular structures of caesium N-(carbamoylethyl)iminodiacetatooxoperoxovanadate(V) monohydrate
Kuchta, L
Sivák, M
Marek, J
Pavelcik, F
Casny, M
NEW JOURNAL OF CHEMISTRY, 1999, 23 (01) : 43 - 46
[37] Troublesome crystal structures. Prevention, detection, and resolution
Harlow, RL
JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY, 1996, 101 (03) : 327 - 339
[38] AKIRA, AN EXPERT SYSTEM TO PREDICT CRYSTAL STRUCTURES.
Hosoya, Masahiko
Chinen, Hiroya
Nakamoto, Makoto
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C92 - C92
[39] Asymmetrically Substituted Distyrylbenzenes and Their Polar Crystal Structures.
Blockhuys, Frank
De Borger, Roeland
Collas, Alain
Vande Velde, Christophe M. L.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2010, 66 : S221 - S221
[40] ANOMALOUS RADIATION STABILITY OF LOOSE CRYSTAL STRUCTURES.
Koshkin, V.M.
Dmitriev, Yu.N.
Zabrodskii, Yu.R.
Tarnopol'skaya, R.A.
Ulmanis, U.A.
Soviet physics. Semiconductors, 1984, 18 (08): : 860 - 863

← 1 2 3 4 5 →