2,5-Bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrolyl Complexes of the Divalent Lanthanides: Synthesis and Structures

被引：25
|
作者：
Jenter, Jelena [1 ]
Gamer, Michael T. [1 ]
Roesky, Peter W. [1 ]
机构：
[1] Karlsruher Inst Technol KIT, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 19期
关键词：
X-RAY CHARACTERIZATION; CRYSTAL-STRUCTURES; COORDINATION CHEMISTRY; MOLECULAR-STRUCTURES; METAL-COMPLEXES; SAMARIUM; LIGANDS; DERIVATIVES; SM; BIS(PHOSPHINIMINO)METHANIDES;
D O I：
10.1021/om100539f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of potassium 2,5-bis{N-(2,6-diisopropylphenyl)intinomethyl}pyrrolyl, ((DIP(2)pyr)K], with the anhydrous lanthanide diiodides resulted in the heteroleptic contplexes [(DIP(2)pyr)Lnl(THF)(3)] (Ln = Sm, Eu, Yb). All complexes are monomeric in the solid state, which is remarkable since samarium and europium complexes tend to form &merle complexes bridged by iodine ions. The (DIP(2)pyr)(-) ligands are coordinated almost symmetrically in a K-3 N, N', N '' mode to the metal center in the Samarium and europium compounds. In contrast, for the terbitIM complex an asymmetric coordination mode was observed.
引用
收藏
页码：4410 / 4413
页数：4
相关论文
共 50 条
  • [21] N,N′-Bis[3,5-bis(2,6-diisopropylphenyl)phenyl]butane-2,3-diimine
    Lohr, Tracy L.
    Piers, Warren E.
    Parvez, Masood
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2281 - U2163
  • [22] Synthesis and structural characterization of 2,5-Bis(N-aryliminomethyl)pyrrolyl complexes of aluminum
    Matsuo, Y
    Tsurugi, H
    Yamagata, T
    Tani, K
    Mashima, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (10) : 1965 - 1968
  • [23] (E)-4-Bromo-2-[(2,6-diisopropylphenyl)-iminomethyl]phenol
    Balamurugan, P.
    Raja, K. Kanmani
    Rani, S. Kutti
    Chakkaravarthi, G.
    Rajagopal, G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1782 - +
  • [24] Bis-coordination of N-(alkyl)-N′-(2,6-diisopropylphenyl) heterocyclic carbenes to Grubbs catalysts
    Ledoux, Nele
    Allaert, Bart
    Linden, Anthony
    Van der Voort, Pascal
    Verpoort, Francis
    ORGANOMETALLICS, 2007, 26 (04) : 1052 - 1056
  • [25] N,N-bis(2,6-diisopropylphenyl)-O-phenylenediimine complexes of iron.
    Light, K
    Harlan, CJ
    Ogrin, D
    Bott, SJ
    Zemetra, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U992 - U992
  • [26] SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE
    Kolybalov, D. S.
    Sukhikh, T. S.
    Bashirov, D. A.
    Konchenko, S. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (02) : 277 - 284
  • [27] Organoaluminum(III) complexes of the bis-N,N′-(2,6-diisopropylphenyl)imidazolin-2-imine ligand
    Todd, Angela D. K.
    McClennan, William L.
    Masuda, Jason D.
    RSC ADVANCES, 2016, 6 (73) : 69270 - 69276
  • [28] SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE
    D. S. Kolybalov
    T. S. Sukhikh
    D. A. Bashirov
    S. N. Konchenko
    Journal of Structural Chemistry, 2021, 62 : 277 - 284
  • [29] 2-Bromo-4-chloro-6-[(2,6-diisopropylphenyl)iminomethyl]phenol
    Raja, K. Kanmani
    Bilal, I. Mohammed
    Thambidurai, S.
    Rajagopal, G.
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O2265 - U1664
  • [30] Reactivity of titanium imidazolin-2-iminato complexes with 2,6-diisopropylaniline and 2-{(2,6-diisopropylphenyl)-iminomethyl}pyrrole
    Naktode, Kishor
    Das, Suman
    Nayek, Hari Pada
    Panda, Tarun K.
    JOURNAL OF COORDINATION CHEMISTRY, 2018, 71 (24) : 4148 - 4163
12345