Synthesis and structural characterization of 2,5-Bis(N-aryliminomethyl)pyrrolyl complexes of aluminum

被引：34
|
作者：
Matsuo, Y [1 ]
Tsurugi, H [1 ]
Yamagata, T [1 ]
Tani, K [1 ]
Mashima, K [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 10期
关键词：
D O I：
10.1246/bcsj.76.1965
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of tridentate ligands, 2,5-bis(N-aryliminomethyl)pyrroles (la-e), with I equiv of AlMe3 in toluene afforded aluminum dimethyl complexes. AlMe2[2,5-bis(N-aryliminomethyl)pyrrolyl] (2a-e) with the release of one equiv of methane. In solution the aluminum complexes 2a-e showed C-s-symmetry as characterized by their H-1 NMR spectra, while in solid the geometry around the Al atom as crystallographically determined for 2a and 2b was found to a tetrahedral by an amido nitrogen atom of the pyrrolyl anion, a nitrogen atom of one of two imino groups and two methyl groups. The aluminum complex 2e upon activated by one equiv of B(C6F5)(3) became a catalyst for ethylene polymerization (Activity = 80 g-PE/mol-cat.h).
引用
收藏
页码：1965 / 1968
页数：4
相关论文
共 50 条
  • [1] Selective formation of homoleptic and heteroleptic 2,5-bis(N-aryliminomethyl)pyrrolyl yttrium complexes and their performance as initiators of ε-caprolactone polymerization
    Matsuo, Y
    Mashima, K
    Tani, K
    ORGANOMETALLICS, 2001, 20 (16) : 3510 - 3518
  • [2] Selective formation of homoleptic and heteroleptic 2,5-bis(N-aryliminomethyl)pyrrolyl yttrium complexes and their catalytic performance as initiators of ε-caprolactone polymerization.
    Mashima, K
    Matsuo, Y
    Tsurugi, H
    Tani, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U586 - U586
  • [3] Intramolecular benzylation of an imino group of tridentate 2,5-bis(N-aryliminomethyl)pyrrolyl ligands bound to zirconium and hafnium gives amido-pyrrolyl complexes that catalyze ethylene polymerization
    Tsurugi, H
    Matsuo, Y
    Yamagata, T
    Mashima, K
    ORGANOMETALLICS, 2004, 23 (11) : 2797 - 2805
  • [4] 2,5-Bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrolyl Complexes of the Divalent Lanthanides: Synthesis and Structures
    Jenter, Jelena
    Gamer, Michael T.
    Roesky, Peter W.
    ORGANOMETALLICS, 2010, 29 (19) : 4410 - 4413
  • [5] Unusual enhancement of ethylene polymerization activity of benzyl zirconium complexes by benzylation of the imino moiety of 2-(N-aryliminomethyl)pyrrolyl ligand
    Tsurugi, H
    Yamagata, T
    Tani, K
    Mashima, K
    CHEMISTRY LETTERS, 2003, 32 (08) : 756 - 757
  • [6] (2,5-Bis{[(2,6-diisopropylphenyl)imino]methyl}pyrrolyl)yttrium and -lutetium complexes - Synthesis and Structures
    Meyer, Nils
    Kuzdrowska, Magdalena
    Roesky, Peter W.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (09) : 1475 - 1479
  • [7] Synthesis of 2,5-bis(phosphinoylmethyl)- and 2,5-bis(thiophosphinoylmethyl)-thiophenes
    Camus, Jean-Michel
    Pailloux, Sylvie
    Shirima, Cornel Edicome
    Paine, Robert T.
    MAIN GROUP CHEMISTRY, 2011, 10 (01) : 25 - 36
  • [8] Synthesis, structural characterization and catalysis of ruthenium(II) complexes based on 2,5-bis(2′-pyridyl) pyrrole ligand
    Zhong, Yi-Qing
    Xiao, Hui-Qiong
    Yi, Xiao-Yi
    DALTON TRANSACTIONS, 2016, 45 (45) : 18113 - 18119
  • [9] 2,5-Bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrolyl Complexes of the Heavy Alkaline Earth Metals: Synthesis, Structures, and Hydroamination Catalysis
    Jenter, Jelena
    Koeppe, Ralf
    Roesky, Peter W.
    ORGANOMETALLICS, 2011, 30 (06) : 1404 - 1413
  • [10] Formation of polypyrrole from 2,5-bis(2-pyrrolyl)pyrrolidine
    Garsuch, A
    Sattler, RR
    Pickup, PG
    CHEMICAL COMMUNICATIONS, 2004, (03) : 344 - 345
12345