Synthesis and structural characterization of 2,5-Bis(N-aryliminomethyl)pyrrolyl complexes of aluminum

被引：34
|
作者：
Matsuo, Y [1 ]
Tsurugi, H [1 ]
Yamagata, T [1 ]
Tani, K [1 ]
Mashima, K [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 10期
关键词：
D O I：
10.1246/bcsj.76.1965
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of tridentate ligands, 2,5-bis(N-aryliminomethyl)pyrroles (la-e), with I equiv of AlMe3 in toluene afforded aluminum dimethyl complexes. AlMe2[2,5-bis(N-aryliminomethyl)pyrrolyl] (2a-e) with the release of one equiv of methane. In solution the aluminum complexes 2a-e showed C-s-symmetry as characterized by their H-1 NMR spectra, while in solid the geometry around the Al atom as crystallographically determined for 2a and 2b was found to a tetrahedral by an amido nitrogen atom of the pyrrolyl anion, a nitrogen atom of one of two imino groups and two methyl groups. The aluminum complex 2e upon activated by one equiv of B(C6F5)(3) became a catalyst for ethylene polymerization (Activity = 80 g-PE/mol-cat.h).
引用
收藏
页码：1965 / 1968
页数：4
相关论文
共 50 条
  • [31] Copolymers of 2,5-bis[(4-methoxyphenyl) oxycarbonyl]styrene with n-butyl acrylate:: Design, synthesis, and characterization
    Gao, LC
    Pan, QW
    Yi, Y
    Fan, XH
    Chen, XF
    Zhou, QF
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (23) : 5935 - 5943
  • [32] Synthesis of deuterium and 15N-labelled 2,5-bis[5-amidino-2-pyridyl]furan and 2,5-bis[5-(methoxyamidino)-2-pyridyl]furan
    Ismail, Mohamed A.
    Boykin, David W.
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 2006, 49 (11): : 985 - 996
  • [33] Pyrrolyl-, 2-(2-thienyl)pyrrolyl- and 2,5-bis(2-thienyl)pyrrolyl-nucleosides: synthesis, molecular and electronic structure, and redox behaviour of C5-thymidine derivatives
    Galindo, Miguel A.
    Hannant, Jennifer
    Harrington, Ross W.
    Clegg, William
    Horrocks, Benjamin R.
    Pike, Andrew R.
    Houlton, Andrew
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2011, 9 (05) : 1555 - 1564
  • [34] N-Benzyl-2,5-bis(2-thienyl)pyrrole
    Conde, JP
    Elsegood, MRJ
    Ryder, KS
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : O166 - O168
  • [35] Synthesis of poly-[2,5-bis(4′-methoxybenzoyloxy)benzyl acrylate] and poly-[2,5-bis(4′-methoxybenzoyloxy)benzyl methacrylate]
    Mi, QD
    Wan, XH
    Zhou, QF
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2000, 21 (05): : 822 - 824
  • [36] SYNTHESIS AND REACTIVITY OF THE 2,5-BIS(TRIMETHYLSTANNYL) DERIVATIVES OF THIOPHENE AND FURAN
    SEITZ, DE
    LEE, SH
    HANSON, RN
    BOTTARO, JC
    SYNTHETIC COMMUNICATIONS, 1983, 13 (02) : 121 - 128
  • [37] A new synthesis of 2,5-bis(4-cyanophenyl)furan
    Suthiwangcharoen, Nisaraporn
    Stephens, Chad E.
    ARKIVOC, 2006, : 122 - 127
  • [38] Synthesis, Structural Characterization, and Catalytic Activity of Indenyl Tris(N-pyrrolyl)phosphine Complexes of Ruthenium
    Stark, Matthew J.
    Shaw, Michael J.
    Rath, Nigam P.
    Bauer, Eike B.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (07) : 1093 - 1102
  • [39] Regioregular poly[2,5-bis(3-butyl-2-thienyl)tellurophene]: Synthesis and characterization aspects
    Ng, SC
    Ding, H
    Chan, HSO
    CHEMISTRY LETTERS, 1999, (12) : 1325 - 1326
  • [40] Synthesis and characterization of a thermotropic liquid-crystalline poly[2,5-bis(4′alkoxycarbonylphenyl)styrene]
    Zhu, Zhiguo
    Zhi, Junge
    Liu, Anhua
    Cui, Jiaxi
    Tang, Hui
    Qiao, Wenqiang
    Wan, Xinhua
    Zhou, Qifeng
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (05) : 830 - 847
12345