Structural characterizations and magnetic properties of three new reduced molybdenum phosphates

被引：40

作者：

Zhang, Xiao ^{[1
]}

Xu, Ji-Qing ^{[1
]}

Yu, Jie-Hui ^{[1
]}

Lu, Jing ^{[1
]}

Xu, Yan ^{[1
]}

Chen, Yan ^{[1
]}

Wang, Tie-Gang ^{[1
]}

Yu, Xiao-Yang ^{[1
]}

Yang, Qing-Feng ^{[1
]}

Hou, Qin ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Syth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2007年 / 180卷 / 06期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; polyoxometalate; crystal structure; organic-inorganic hybrid material;

D O I：

10.1016/j.jssc.2007.02.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new molybdophosphates, [Co(dien)(2)] center dot (H(3)dien)(6) center dot {[CoMo12O24(OH)(6)(HPO4)(2)(PO4)(6)][Co(Hdien)](2)[CoMo12O24(OH)(6)(PO4)(8)]} center dot (dien) center dot 4H(3)O center dot 5H(2)O (1), (H(3)dien)(4)[MMo12O24(OH)(6)(HPO4)(4)(PO4)(4)] center dot 10H(2)O [M = Co for (2), Ni for (3); dien = diethylenetriamine], have been synthesized by employing hydrothermal method and characterized by single crystal X-ray diffraction. Compound I is built up of Co[P4Mo6](2) units as the structural motif covalently linked by [Co(Hdien)] complex subunits to yield an unusual 1-D chain. Compounds 2 and 3 are isomorphic and both display covalent discrete M[P4Mo6](2) cluster structures which are linked by the hydrogen bonds to form 3-D supramolecular networks. Both 1 and 2 display antiferromagnetic interaction and these three compounds all exhibit intensive photoluminescence. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：1949 / 1956

页数：8

共 50 条

[41] Magnetic properties of titanium phosphates and titanium silicophosphates
Benmoussa, A
Michel, C
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX, 1999, 24 (03): : 233 - 240
[42] Magnetic and structural characterizations on nanoparticles of FePt, FeRh and their composites
Ko, Hnin Yu Yu
Suzuki, Takao
Nam, Nguyen T.
Phuoc, Nguyen N.
Cao, Jiangwei
Hirotsu, Yoshihiko
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (22) : 3120 - 3123
[43] Structural characterizations and optical properties of new Li-Sr-Nb-phosphate glasses
Lee, Yi-Mu
Hsu, S. M.
Yung, S. W.
Zhang, T.
Huang, Y. S.
Wu, J. J.
Hsu, C. H.
Chin, T. S.
MATERIALS CHEMISTRY AND PHYSICS, 2014, 144 (03) : 235 - 241
[44] STRUCTURAL STUDIES OF SOME NEW THORIUM PHOSPHATES
SLJUKIC, M
KOJICPRODIC, B
RUZICTOROS, Z
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1978, 34 : S169 - S170
[45] ELECTROCHEMICAL PREPARATION OF NEW REDUCED MOLYBDENUM OXIDES
SCHNEEMEYER, LF
SPENGLER, SE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 196 - INOR
[46] Mechanical and magnetic properties of a new austenitic structural steel
Putatunda, SK
Unni, S
Lawes, G
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 406 (1-2): : 254 - 260
[47] STRUCTURAL AND MAGNETIC PROPERTIES OF NEW ORGANOMETALLIC VANADIUM COMPOUNDS
Ramos Silva, M.
Paixao, J. A.
Matos Beja, A.
Alte da Veiga, L.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 426 - 426
[48] Synthesis, structural, and stereogenic characterizations of new trispirocyclotriphosphazenes
Tumer, Yasemin
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2022, 69 (11) : 1897 - 1907
[49] MAGNETIC PROPERTIES OF POLYCRYSTALLINE MOLYBDENUM DISULFIDES
BELOUGNE, P
ZANCHETTA, JV
ROUILLON, JC
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1973, 70 (04) : 682 - 683
[50] CRYSTALLOGRAPHIC AND MAGNETIC PROPERTIES OF A NEW OXYGENATED MOLYBDENUM COMPOUND, NAMO02
RINGENBA.C
KESSLER, H
HATTERER, A
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1969, 269 (22): : 1394 - &

← 1 2 3 4 5 →