Structural characterizations and magnetic properties of three new reduced molybdenum phosphates

被引：40

作者：

Zhang, Xiao ^{[1
]}

Xu, Ji-Qing ^{[1
]}

Yu, Jie-Hui ^{[1
]}

Lu, Jing ^{[1
]}

Xu, Yan ^{[1
]}

Chen, Yan ^{[1
]}

Wang, Tie-Gang ^{[1
]}

Yu, Xiao-Yang ^{[1
]}

Yang, Qing-Feng ^{[1
]}

Hou, Qin ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Syth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2007年 / 180卷 / 06期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; polyoxometalate; crystal structure; organic-inorganic hybrid material;

D O I：

10.1016/j.jssc.2007.02.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new molybdophosphates, [Co(dien)(2)] center dot (H(3)dien)(6) center dot {[CoMo12O24(OH)(6)(HPO4)(2)(PO4)(6)][Co(Hdien)](2)[CoMo12O24(OH)(6)(PO4)(8)]} center dot (dien) center dot 4H(3)O center dot 5H(2)O (1), (H(3)dien)(4)[MMo12O24(OH)(6)(HPO4)(4)(PO4)(4)] center dot 10H(2)O [M = Co for (2), Ni for (3); dien = diethylenetriamine], have been synthesized by employing hydrothermal method and characterized by single crystal X-ray diffraction. Compound I is built up of Co[P4Mo6](2) units as the structural motif covalently linked by [Co(Hdien)] complex subunits to yield an unusual 1-D chain. Compounds 2 and 3 are isomorphic and both display covalent discrete M[P4Mo6](2) cluster structures which are linked by the hydrogen bonds to form 3-D supramolecular networks. Both 1 and 2 display antiferromagnetic interaction and these three compounds all exhibit intensive photoluminescence. (c) 2007 Elsevier Inc. All rights reserved.

引用

页码：1949 / 1956

页数：8

共 50 条

[21] Synthesis, crystal structure and magnetic properties of new molybdenum(V) phosphates containing Mn2+ or Co2+ with three-dimensional structures directed by the nature of the transition metal
du Peloux, C
Mialane, P
Dolbecq, A
Marrot, J
Rivière, E
Sécheresse, F
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) : 3392 - 3396
[22] Structural characterizations of lithium gallium phosphates, analogous to the amblygonite-montebrasite series
Beitone, L
Guillou, N
Millange, F
Loiseau, T
Férey, G
SOLID STATE SCIENCES, 2002, 4 (08) : 1061 - 1065
[23] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES
HAUSHALTER, RC
MUNDI, LA
CHEMISTRY OF MATERIALS, 1992, 4 (01) : 31 - 48
[24] Electronic properties of reduced molybdenum oxides
Inzani, K.
Nematollahi, M.
Vullum-Bruer, F.
Grande, T.
Reenaas, T. W.
Selbach, S. M.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (13) : 9232 - 9245
[25] Structural, magnetic, and magnetocaloric properties of triangular-lattice transition-metal phosphates
Zhang, Chuandi
Xiang, Junsen
Zhu, Quanliang
Wu, Longfei
Zhang, Shanfeng
Xu, Juping
Yin, Wen
Sun, Peijie
Li, Wei
Su, Gang
Jin, Wentao
PHYSICAL REVIEW MATERIALS, 2024, 8 (04):
[26] Hydrothermal synthesis of MnO2 nanowires: structural characterizations, optical and magnetic properties
Arbab Mohammad Toufiq
Fengping Wang
Qurat-ul-ain Javed
Quanshui Li
Yan Li
Applied Physics A, 2014, 116 : 1127 - 1132
[27] Hydrothermal synthesis of MnO2 nanowires: structural characterizations, optical and magnetic properties
Toufiq, Arbab Mohammad
Wang, Fengping
Javed, Qurat-ul-ain
Li, Quanshui
Li, Yan
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2014, 116 (03): : 1127 - 1132
[28] Structural, magnetic and corrosion properties of electrodeposited cobalt-nickel-molybdenum alloys
Gómez, E
Pellicer, E
Vallés, E
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (03) : 275 - 281
[29] Textural characterizations and catalytic properties of quasispherical nanosized molybdenum disulfide
Farag, Hamdy
Al-Megren, Hamid
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 332 (02) : 425 - 431
[30] Structural and magnetic properties of new RRuGe compounds
Morozkin, AV
Nikitin, SA
Seropegin, YD
Sviridov, IA
Tskhadadze, IA
JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 268 (1-2) : L1 - L2

← 1 2 3 4 5 →