Oligomerization reactions of 1-hexene with metallocene catalysts: Detailed data on reaction chemistry and kinetics

被引：8
|
作者：
Kissin, Yury V. [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, 123 Bevier Rd, Piscataway, NJ 08854 USA
来源：
MOLECULAR CATALYSIS | 2019年 / 463卷
关键词：
Oligomer; Metallocene catalysts; Hexene; Kinetics; Gas chromatography; GAS-CHROMATOGRAPHIC ANALYSIS; POLYMERIZATION; PROPENE; OLEFIN; COCATALYSTS; MECHANISM; MODEL;
D O I：
10.1016/j.mcat.2018.11.013
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper describes oligomerization reactions of 1-hexene with catalysts derived from three metallocene complexes, Cp2ZrCl2, (CH3-Cp)(2)ZrCl2 and (n-C4H9-Cp)(2)ZrCl2, and two types of methylalumoxane. Gas chromatographic analysis of oligomers provides detailed information on the chemical structure of individual oligomer molecules, the chemical mechanism and kinetics of early stages of the oligomerization reactions.
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页码：87 / 93
页数：7
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