Oligomerization reactions of 1-hexene with metallocene catalysts: Detailed data on reaction chemistry and kinetics

被引：8
|
作者：
Kissin, Yury V. [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, 123 Bevier Rd, Piscataway, NJ 08854 USA
来源：
MOLECULAR CATALYSIS | 2019年 / 463卷
关键词：
Oligomer; Metallocene catalysts; Hexene; Kinetics; Gas chromatography; GAS-CHROMATOGRAPHIC ANALYSIS; POLYMERIZATION; PROPENE; OLEFIN; COCATALYSTS; MECHANISM; MODEL;
D O I：
10.1016/j.mcat.2018.11.013
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper describes oligomerization reactions of 1-hexene with catalysts derived from three metallocene complexes, Cp2ZrCl2, (CH3-Cp)(2)ZrCl2 and (n-C4H9-Cp)(2)ZrCl2, and two types of methylalumoxane. Gas chromatographic analysis of oligomers provides detailed information on the chemical structure of individual oligomer molecules, the chemical mechanism and kinetics of early stages of the oligomerization reactions.
引用
收藏
页码：87 / 93
页数：7
相关论文
共 50 条
  • [21] 1-hexene oligomerization by fluorinated tin dioxide
    Yurkova, L. L.
    Lermontov, S. A.
    Malkova, A. N.
    Baranchikov, A. E.
    Ivanov, V. K.
    INORGANIC MATERIALS, 2014, 50 (05) : 479 - 481
  • [22] KINETICS OF 1-HEXENE POLYMERIZATION
    DANDGE, DK
    HELLER, JP
    LIEN, C
    WILSON, KV
    JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (06) : 5373 - 5383
  • [23] 1,3-Double Siloxo-Bridged Zirconium Metallocene for Propene and 1-Hexene Regioselective Oligomerization
    Londaitsbehere, Addis
    Cuenca, Tomas
    Mosquera, Marta E. G.
    Cano, Jesus
    Milione, Stefano
    Grassi, Alfonso
    ORGANOMETALLICS, 2012, 31 (05) : 2108 - 2111
  • [24] OLIGOMERIZATION OF 1-HEXENE WITH BIMETALLIC CATALYSTS BASED ON TITANIUM OR ZIRCONIUM DERIVATIVES AND ORGANOALUMINUM COMPOUNDS
    LIU, HQ
    DEFFIEUX, A
    SIGWALT, P
    POLYMER BULLETIN, 1990, 24 (04) : 355 - 362
  • [25] Chromium catalysts for selective ethylene oligomerization to 1-hexene and 1-octene: Recent results
    Alferov, Kirill A.
    Belov, Gennadiy P.
    Meng, Yuezhong
    APPLIED CATALYSIS A-GENERAL, 2017, 542 : 71 - 124
  • [26] Ethylene/1-Hexene Copolymerization Kinetics and Microstructure of Copolymers Made with a Supported Metallocene Catalyst
    Mehdiabadi, Saeid
    Lhost, Olivier
    Vantomme, Aurelien
    Soares, Joao B. P.
    MACROMOLECULAR REACTION ENGINEERING, 2021, 15 (06)
  • [27] Liquid-phase oligomerization of 1-hexene using Al-MTS catalysts
    Escola, J. M.
    Van Grieken, R.
    Moreno, J.
    Rodriguez, R.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (22) : 7409 - 7414
  • [28] HYDROGENATION OF 1-HEXENE BY RHODIUM CATALYSTS
    PAJARES, JA
    REYES, P
    ORO, LA
    SARIEGO, R
    JOURNAL OF MOLECULAR CATALYSIS, 1981, 11 (2-3): : 181 - 192
  • [29] Living polymerization of propylene and 1-hexene using bis-Cp type metallocene catalysts
    Fukui, Y
    Murata, M
    Soga, K
    MACROMOLECULAR RAPID COMMUNICATIONS, 1999, 20 (12) : 637 - 640
  • [30] Copolymerization of ethylene with 1-hexene or 1-hexadecene over siloxy-substituted metallocene catalysts
    Härkki, O
    Lehmus, P
    Leino, R
    Luttikhedde, HJG
    Näsman, JH
    Seppälä, JV
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (06) : 1561 - 1565
12345